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(1R)-(+)-ALPHA-PINENE

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(1R)-(+)-ALPHA-PINENE Basic information

Product Name:
(1R)-(+)-ALPHA-PINENE
Synonyms:
  • (+)-ALPHA-PINENE (MIXTURE OF ISOMERS)
  • (1R,5R)-2-6,6-TRIMETHYL-BICYCLO[3.1.1]HEPT-2-ENE
  • (1R,5R)-2-PINENE
  • (1R)-(+)-ALPHA-PINENE
  • (1R)-(+)-a-pinene
  • (+)-A-PINENE
  • FEMA 2902
  • D-ALPHA PINENE
CAS:
7785-70-8
MF:
C10H16
MW:
136.23
EINECS:
232-087-8
Product Categories:
  • Bicyclic Monoterpenes
  • Biochemistry
  • Industrial/Fine Chemicals
  • Terpenes
Mol File:
7785-70-8.mol
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(1R)-(+)-ALPHA-PINENE Chemical Properties

Melting point:
−62 °C(lit.)
Boiling point:
155-156 °C(lit.)
Density 
0.858 g/mL at 20 °C(lit.)
vapor pressure 
5 hPa (25 °C)
FEMA 
2902 | ALPHA-PINENE
refractive index 
n20/D 1.465(lit.)
Flash point:
91 °F
storage temp. 
Store at +2°C to +8°C.
form 
Liquid
color 
Clear colorless
Odor
at 10.00 % in dipropylene glycol. harsh terpene aromatic minty
Odor Type
herbal
explosive limit
0.8-6%(V)
optical activity
[α]22/D +47.1°, neat
Water Solubility 
Soluble in Ether, Alcohols, Chloroform. Not miscible in water.
Merck 
14,7445
JECFA Number
1329
BRN 
3648264
Dielectric constant
2.7(20℃)
InChIKey
GRWFGVWFFZKLTI-UHFFFAOYSA-N
LogP
4.44-4.46 at 20-37℃
CAS DataBase Reference
7785-70-8(CAS DataBase Reference)
EPA Substance Registry System
Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl-, (1R,5R)- (7785-70-8)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
26-36-16-23
RIDADR 
UN 2368 3/PG 3
WGK Germany 
3
RTECS 
DT7000000
10
Autoignition Temperature
491 °F
TSCA 
Yes
HS Code 
2902 19 00
HazardClass 
3
PackingGroup 
III

MSDS

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(1R)-(+)-ALPHA-PINENE Usage And Synthesis

Chemical Properties

(1R)-(+)-ALPHA-PINENE is Clear colourless liquid

Uses

(1R)-(+)-α-Pinene is used in hydroboration reactions and the reduction of ketones.

Uses

(+)-alpha-Pinene is employed in the preparation of chiral hydroboration reagents. It is a bronchodilator in humans. α-Pinene is an anti-inflammatory and used as a broad-spectrum antibiotic.It exhibits activity as an acetylcholinesterase inhibitor, aiding memory. It is a biosynthetic base for CB2 ligands, such as HU-308.

Uses

(+)-α-Pinene has been used in a tolerance testing procedure to detect the genes in Marinobacter aquaeolei, for engineering a pinene tolerant Escherichia coli.

Definition

ChEBI: The (+)-enantiomer of alpha-pinene.

General Description

(+)-α-Pinene is a monoterpenoid compound mainly found in Pinus species.

Flammability and Explosibility

Flammable

Purification Methods

(1R)-(+)-ALPHA-PINENE is isomerised by heat, acids and certain solvents. It should be distilled under reduced pressure under nitrogen and stored in the dark. It has been purified via the nitrosochloride [Waterman et al. Recl Trav Chim, Pays-Bas 48 1191 1929]. For purification of optically active forms see Lynn [J Am Chem Soc 91 361 1919].

(1R)-(+)-ALPHA-PINENE Preparation Products And Raw materials

Preparation Products

(1R)-(+)-ALPHA-PINENESupplier

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