ChemicalBook > Product Catalog > Organic Chemistry > Phosphines > 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Basic information
- Product Name:
- 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
- Synonyms:
-
- 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
- 2,2'-BIS(DIPHENYLPHOSPHINO)BIPHENYL
- BIPHEP
- [2-(2-diphenylphosphinophenyl)phenyl]-diphenylphosphine
- 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98%BIPHEP
- 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl, (BIPHEP)
- 2,2’-Bis(diphenylphospino)-1,1’-biphenyl
- PHOSPHINE, 1,1''-[[1,1''-BIPHENYL]-2,2''-DIYL]BIS[1,1-DIPHENYL-
- CAS:
- 84783-64-2
- MF:
- C36H28P2
- MW:
- 522.55
- Product Categories:
-
- Achiral Phosphine
- Aryl Phosphine
- Phosphines
- Biphenyl & Diphenyl ether
- Phosphine Ligands
- Synthetic Organic Chemistry
- Mol File:
- 84783-64-2.mol
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2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chemical Properties
- Melting point:
- 210-214 °C
- Boiling point:
- 635.5±48.0 °C(Predicted)
- solubility
- soluble in Toluene
- form
- crystal
- color
- white
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38-36
- Safety Statements
- 37/39-26
- TSCA
- No
- HS Code
- 29310099
MSDS
- Language:English Provider:ACROS
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2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Usage And Synthesis
Reaction
- Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones.
- Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions
- Useful ligand for palladium-catalyzed synthesis of butatrenes.
- Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation.
- Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation.
- Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation.
- Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes.
- Ruthenium-catalyzed synthesis of indoles.
- Ruthenium-catalyzed oxidative cyclization.
- Rhodium-catalyzed boron arylation.
Chemical Properties
white crystalline powder or crystals
Uses
2,2''-Bis(diphenylphosphino)-1,1’-biphenyl (CAS# 84783-64-2) is a chelating phosphine and has been used to study the effects of bite angles on the chemical and physical properties of transition metal complexes. 2,2''-Bis(diphenylphosphino)-1,1’-biphenyl appears as a catalytic ligand in Ni- and Pd-Catalyzed cross-electrophile coupling reactions to form highly substituted 1,3-dienes.
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYLSupplier
J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
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- 021-67121386
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2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL(84783-64-2)Related Product Information
- 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
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- (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
- [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride
- (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
- R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
- 3',6'-BIS(DIETHYLAMINO)-2-(4-NITROPHENYL)SPIRO[ISOINDOLE-1,9'-XANTHENE]-3-ONE
- Diphenylphosphine
- DICHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(R)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)
- PHOSPHINE OXIDE, [1,1'-BINAPHTHALENE]-2,2'-DIYLBIS
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)
- DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)
- (R)-H8-BINAP
- (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
- (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
- Chloro[(R)-(+)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl](p-cymene)ruthenium(II)chlorideCH2Cl2adduct