DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)
DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) Basic information
- Product Name:
- DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)
- Synonyms:
-
- DICHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(2S)-(+)-1,1-BIS(4-METHOXYPHENYL)-3-METHYL-1,2-BUTANEDIAMINE]
- DICHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1-BINAPHTHYL][(2S)-(+)-1,1-BIS(4-METHOXYPHENYL)-3-METHYL-1,2-BUTANEDIAMINE]RUTHENIUM(II)
- DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)
- DICHLORO[(S)-BINAP][(S)-DAIPEN]RUTHENIUM(II)
- Dichlorobisdiphenylphosphinobinaphthylbismethoxyphenylmethylbutanediam
- dichloro[(s)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2s)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediami
- Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)dichloromethaneadduct,min.97%
- Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct, min. 97%
- CAS:
- 212143-24-3
- MF:
- C63H58Cl2N2O2P2Ru
- MW:
- 1109.07
- Mol File:
- 212143-24-3.mol
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DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) Chemical Properties
- Melting point:
- >100°C
- storage temp.
- 0-6°C
- form
- Powder
- color
- white to pale yellow
- Sensitive
- air sensitive, store cold
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Safety Information
- Safety Statements
- 22-24/25
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DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) Usage And Synthesis
Reactions
The NOYORI catalysts are a ruthenium-based system containing a phosphine and 1,2-diamine ligand. The catalysts are used in the highly-efficient, enantio and diastereoselective hydrogenation of simple ketones, usually under the mild conditions of room temperature and 1-10 atm of hydrogen pressure.
DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)Supplier
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DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)(212143-24-3)Related Product Information
- (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
- DICHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(R)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)
- Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
- 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
- (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
- (2S,3S)-(-)-2,3-BUTANEDIAMINE DIHYDROCHLORIDE
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
- 2-(4-METHOXYPHENYL)-2-PHENYLETHYLAMINE HYDROCHLORIDE
- (S)-(-)-2-AMINO-3-METHYL-1,1-DIPHENYLBUTANE
- DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)
- C-(4-METHOXY-PHENYL)-C-PHENYL-METHYL-AMMONIUM CHLORIDE
- 2,2-BIS(4-METHOXYLPHENYL)ETHYLAMINE
- (S)-Daipen