DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Chemical Properties

Melting point:

230-235°C

storage temp. 

Inert atmosphere,Room Temperature

form 

Powder

color 

white

InChI

InChI=1S/2C18H15P.2CO.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2;;;/h2*1-15H;;;2*1H;/q;;;;;;+2/p-2

InChIKey

PXURRFCLQDNZOY-UHFFFAOYSA-L

SMILES

P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.[Ru](Cl)Cl.[O+]#[C-].[O+]#[C-]

CAS DataBase Reference

14564-35-3

EPA Substance Registry System

Ruthenium, dicarbonyldichlorobis(triphenylphosphine)- (14564-35-3)

Safety Information

Hazard Codes 

Xn

Risk Statements 

20/21/22-36/37/38

Safety Statements 

22-24/25

WGK Germany 

3

TSCA 

TSCA listed

HS Code 

28439090

Storage Class

11 - Combustible Solids

MSDS

• Language:English Provider:SigmaAldrich

DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Usage And Synthesis

Uses

Dichlorodicarbonylbis(triphenylphosphine)ruthenium exhibits good catalytic performance in the addition reaction of aromatic ketone carbonyl groups with olefin molecules, and can be widely used as a noble metal catalyst in organic synthesis reactions.

Chemical Properties

white crystals

reaction suitability

core: ruthenium
reagent type: catalyst

Synthesis

A certain amount of triphenylphosphine was weighed and added to a 100mL three-necked flask having a quantitative anhydrous ethanol solution, stirred, and heated to boiling, then a certain amount of ruthenium trichloride trihydrate, formaldehyde solution, and potassium hydroxide were added to the three-necked flask in rapid succession. The reaction was heated to reflux (precipitates were produced during the reaction), the reaction was stopped after a period of time, naturally cooled to room temperature and filtered. The filter cake was washed with 95% ethanol, deionized water, 95% ethanol and petroleum ether in sequence, and the precipitate was dried to constant weight to obtain the crude product of dichlorodicarbonylbis(triphenylphosphine)ruthenium, weighed, and the product yield was calculated.

DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)(14564-35-3)Related Product Information

• Dicarbonylacetylacetonato rhodium(I)
• Dichloro(1,5-cyclooctadiene)platinum(II)
• Dichloro(1,5-cyclooctadien)ruthenium(II) polymer
• Diphenyl(1,5-cyclooctadiene) platinum(II)
• Dichlorobis[chloro(cyclohexene)platinum(II)
• DIBROMO(1,5-CYCLOOCTADIENE)PLATINUM(II)
• Carbonylchlorohydrotris(triphenylphosphine)ruthenium
• Carbonyldihydrotris(triphenylphosphine)ruthenium
• Triphenylphosphine
• Diphenylphosphine
• Ruthenium
• DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
• (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE
• CARBON MONOXIDE
• TRIPHENYLPHOSPHINE HYDROCHLORIDE