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Carbonylchlorohydrotris(triphenylphosphine)ruthenium

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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Basic information

Product Name:
Carbonylchlorohydrotris(triphenylphosphine)ruthenium
Synonyms:
  • CARBONYLCHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
  • carbonylchlorohydridotris(triphenyl-phosphine)rut
  • carbonylchlorohydrotris(triphenylphosphine)ruthenium
  • Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium
  • Carbonylchlorohydridotris(triphenylphosphine)ruthenium
  • Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II),99%
  • Ru(CO)ClH(PPh3)3
  • RuHCl(CO)(PPh3)3
CAS:
16971-33-8
MF:
C55H45ClOP3Ru
MW:
951.39
EINECS:
241-051-0
Product Categories:
  • Ru
  • metal carbonyl complex
  • Catalysis and Inorganic Chemistry
  • Ru Catalysts
  • Ruthenium
Mol File:
16971-33-8.mol
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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Chemical Properties

Melting point:
204-206 °C (dec.)(lit.)
Boiling point:
approximate 360℃
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Powder
color 
Cream to tan
Water Solubility 
insoluble
Sensitive 
Air stable, light sensitive
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Safety Information

Hazard Codes 
Xn,T
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-37/39-36/37/39-22
WGK Germany 
3
HS Code 
29310099

MSDS

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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Usage And Synthesis

Reaction

  1. Catalyst for alcohol α-allylation with dienes or allenes under transfer hydrogenation conditions.
  2. Catalyst for tandem isomerization (to imine), followed by Friedel Crafts alkylation.
  3. Catalyst for amination of alcohols with ammonia.

Chemical Properties

pale yellow crystals

Uses

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).

Carbonylchlorohydrotris(triphenylphosphine)rutheniumSupplier

Shanghai Incat Chemtech Co.,Ltd. Gold
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021-57603038 13601791340
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917-917-8888777 18691746767
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Beijing Guofang Dingsheng Technology Co., Ltd. Gold
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0316-6175846 18610472091
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J & K SCIENTIFIC LTD.
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4006608290; 18621169109
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