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Carbonylchlorohydrotris(triphenylphosphine)ruthenium
Carbonylchlorohydrotris(triphenylphosphine)ruthenium Basic information
- Product Name:
- Carbonylchlorohydrotris(triphenylphosphine)ruthenium
- Synonyms:
-
- CARBONYLCHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
- carbonylchlorohydridotris(triphenyl-phosphine)rut
- carbonylchlorohydrotris(triphenylphosphine)ruthenium
- Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium
- Carbonylchlorohydridotris(triphenylphosphine)ruthenium
- Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II),99%
- Ru(CO)ClH(PPh3)3
- RuHCl(CO)(PPh3)3
- CAS:
- 16971-33-8
- MF:
- C55H45ClOP3Ru
- MW:
- 951.39
- EINECS:
- 241-051-0
- Product Categories:
-
- Ru
- metal carbonyl complex
- Catalysis and Inorganic Chemistry
- Ru Catalysts
- Ruthenium
- Mol File:
- 16971-33-8.mol
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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Chemical Properties
- Melting point:
- 204-206 °C (dec.)(lit.)
- Boiling point:
- approximate 360℃
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- Powder
- color
- Cream to tan
- Water Solubility
- insoluble
- Sensitive
- Air stable, light sensitive
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Safety Information
- Hazard Codes
- Xn,T
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-37/39-36/37/39-22
- WGK Germany
- 3
- HS Code
- 29310099
MSDS
- Language:English Provider:SigmaAldrich
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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Usage And Synthesis
Reaction
- Catalyst for alcohol α-allylation with dienes or allenes under transfer hydrogenation conditions.
- Catalyst for tandem isomerization (to imine), followed by Friedel Crafts alkylation.
- Catalyst for amination of alcohols with ammonia.
Chemical Properties
pale yellow crystals
Uses
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).
Carbonylchlorohydrotris(triphenylphosphine)rutheniumSupplier
Shanghai Incat Chemtech Co.,Ltd. Gold
- Tel
- 021-57603038 13601791340
- 307593986@qq.com
Shaanxi Rock New Materials Co., Ltd. Gold
- Tel
- 0917-8888777, 3380777,18691786767; 15619786767
- xuya@bjrock.com
Beijing Guofang Dingsheng Technology Co., Ltd. Gold
- Tel
- 18610472091 18610472091
- gfdskj@163.com
Leshan Bangsheng New Materials Co., Ltd Gold
- Tel
- 0833-2599138 19162614312
- lsbangsheng@126.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
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Carbonylchlorohydrotris(triphenylphosphine)ruthenium(16971-33-8)Related Product Information
- METHOXYCARBONYLSULFENYL CHLORIDE
- Ruthenium
- Tris(triphenylphosphine)rhodiu
- Ruthenium(III) chloride
- Triphenylphosphine
- Tris(dibenzylideneacetone)dipalladium
- Tris(dibenzylideneacetone)dipalladium
- Hexachloroiridic acid hexahydrate
- Tris(triphenylphosphine)ruthenium(II) chloride
- Rhodium (triphenylphosphine)carbonylacetylacetonate
- Iridium(III) acetylacetonate
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- Chloroplantinic acid
- Platinum dioxide
- Palladium (II) Acetate
- DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
- Carbonyldihydrotris(triphenylphosphine)ruthenium
- CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)