Basic information Safety Supplier Related

1,4-BIS-MALEIMIDOBUTANE

Basic information Safety Supplier Related

1,4-BIS-MALEIMIDOBUTANE Basic information

Product Name:
1,4-BIS-MALEIMIDOBUTANE
Synonyms:
  • N,N'-(1,4-Butanediyl)di(maleimide)
  • N,N'-Tetramethylenebis(maleimide)
  • 1-(4-maleimidobutyl)-3-pyrroline-2,5-quinone
  • 1-[4-(2,5-dioxopyrrol-1-yl)butyl]pyrrole-2,5-dione
  • TetraMethylenebisMaleiMide
  • TetraMethylenediMaleiMide
  • 1H-Pyrrole-2,5-dione, 1,1'-(1,4-butanediyl)bis-
  • 1,4-Bis-MaleiMidobutane(BMB)
CAS:
28537-70-4
MF:
C12H12N2O4
MW:
248.23
Product Categories:
  • Homobifunctional Crosslinker
  • pharmacetical
  • Maleimide Derivatives
  • Cross Linking Reagents
  • MTS & Sulfhydryl Active Reagents
Mol File:
28537-70-4.mol
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1,4-BIS-MALEIMIDOBUTANE Chemical Properties

Melting point:
196-197°C
Boiling point:
450.3±28.0 °C(Predicted)
Density 
1.388±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
solubility 
Chloroform
form 
Solid
pka
-1.93±0.20(Predicted)
color 
White to Off-White
Appearance
White solid
BRN 
1538100
InChI
InChI=1S/C12H12N2O4/c15-9-3-4-10(16)13(9)7-1-2-8-14-11(17)5-6-12(14)18/h3-6H,1-2,7-8H2
InChIKey
WXXSHAKLDCERGU-UHFFFAOYSA-N
SMILES
C(N1C(=O)C=CC1=O)CCCN1C(=O)C=CC1=O
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2922.49.8000

MSDS

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1,4-BIS-MALEIMIDOBUTANE Usage And Synthesis

Chemical Properties

Off-White Powder

Uses

A short, sulfhydryl reactive homobifunctional crosslinking reagent

Synthesis

1449655-98-4

28537-70-4

General method: 1,4-bis(bromomethyl)benzene (1 mol) was dissolved in 1,1,2,2-tetrachloroethane in an open-ended flask with continuous stirring at 120°C for 12 hours. The reaction process was monitored by thin layer chromatography (TLC). When the reaction was complete, the solvent was removed by evaporation under reduced pressure to give 1,4-bis(maleimido)butane (BMI).

References

[1] Tetrahedron Letters, 2013, vol. 54, # 37, p. 5011 - 5013

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