ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Basic information
- Product Name:
- (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
- Synonyms:
-
- (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine
- (R)-(S)-cy2PF-PtBu2
- (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
- Ferrocene,1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)-,(2R)-
- (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%
- (Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine
- Josiphos SL-J009-1 / (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine
- (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl] ethyldi-t-butylphosphine, min. 97%
- CAS:
- 158923-11-6
- MF:
- C32H52FeP2 10*
- MW:
- 554.55
- EINECS:
- 238-086-9
- Product Categories:
-
- organophosphine ligand
- Chiral Phosphine
- Ferrocene Series
- Josiphos Series
- Mol File:
- 158923-11-6.mol
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(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Chemical Properties
- Melting point:
- 118-120oC
- alpha
- -185° ±10° (c 0.5, CHCl3)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Chloroform (Slightly), Methanol (Very Slightly)
- form
- Powder
- color
- orange
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Safety Information
- Safety Statements
- 22-24/25
- WGK Germany
- 3
- HS Code
- 29319090
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(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Usage And Synthesis
Reaction
- Ligand for Palladium-catalyzed C-N cross-coupling.
- Ligand for Palladium-catalyzed C-S cross-coupling.
- Ligand for Palladium-catalyzed Kumada couplings of aryl and vinyl tosylates.
- Ligand for Rhodium-catalyzed hydroacylation of cyclopropenes, an enatioselective desymmetrization method.
- Ligand for Palladium-catalyzed C-O cross-coupling.
- Ligand for Rhodium-catalyzed coupling of imidazole derivatives with terminal allenes.
- Ligand for Ruthenium-catalyzed C-C coupling of alkynes and alcohols to form branched products of carbonyl allylation
Chemical Properties
Orange powder
Uses
It may be used as a ligand in the palladium catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates.
General Description
sold in collaboration with Solvias AG
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINESupplier
Xinxiang Runyu Material Co., Ltd. Gold
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- 166-166-37336996 15690792173
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- 0917-8888777, 3380777,18691786767; 15619786767
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- 0371-65511006 18625597674
- sales@kingorgchem.com
J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
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(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE(158923-11-6)Related Product Information
- (R)-1-[3,5-Bis(trifluoromethyl)phenyl]ethanol
- (R)-1-nonen-3-ol
- (R)-(-)-1,2,3,4-TETRAHYDRO-1-NAPHTHOL
- (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
- (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE
- (R)-(S)-JOSIPHOS
- (R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
- (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
- Di-tert-butylphosphine
- T-BUTYLPHOSPHINE
- CYCLOHEXYLPHOSPHINE
- Ferrocene
- DICYCLOHEXYLPHOSPHINE
- (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
- 1,3-BIS(DIETHYLPHOSPHINO)PROPANE
- 1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE
- (S)-1-[(R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
- (R)-(-)-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE