Basic information Reaction Safety Supplier Related

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE

Basic information Reaction Safety Supplier Related

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Basic information

Product Name:
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
Synonyms:
  • (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]-ethyl-di-tert-butylphosphine, Manufactured by Solvias AG
  • (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%
  • -2-(Diphenylphosphino)
  • ferrocenyl]ethyldi-tert-butylphosphine
  • "Josiphos SL-J002-1/ (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine"
  • Josiphos SL-J002
  • Josiphos SL-J002-1 / (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
  • (R)1[(1S)2(diphenylphosphino)ferrocenyl] et-di-T-butylphosph
CAS:
155830-69-6
MF:
C32H40FeP210*
MW:
542.45
Product Categories:
  • Chiral Phosphine
  • Ferrocene Series
  • organophosphine ligand
  • Josiphos Series
Mol File:
155830-69-6.mol
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(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties

Melting point:
218-220°C (dec.)
alpha 
-412° ±15° (c 0.5, CHCl3)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform, Methanol
form 
Powder
color 
Orange
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Safety Information

Risk Statements 
20/21/22-36/37/38
Safety Statements 
24/25
WGK Germany 
3
10
HS Code 
29319090

MSDS

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(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Usage And Synthesis

Reaction

  1. Ligand for Palladium-catalyzed amination of aryl halides
  2. Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene
  3. Ligand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids
  4. Ligand for Copper-catalyzed asymmetric 1,4-hydrosilylations of α,β-unsaturated esters
  5. Ligand for Ruthenium-catalyzed asymmetric hydrogenation of N-sulfonated-α-dehydroamino acids
  6. Ligand for Rhodium-catalyzed asymmetric hydrogenation of enamines
  7. Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates
  8. Ligand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides
  9. Ligand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a C-C bond


Chemical Properties

Orange powder

Uses

It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester.

General Description

(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-tBu) is a chiral ferrocenyl diphosphine ligand.

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINESupplier

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