5-Fluoro-2-nitroaniline Chemical Properties

Melting point:

96.0 to 100.0 °C

Boiling point:

295.5±20.0 °C(Predicted)

Density 

1.448±0.06 g/cm3(Predicted)

storage temp. 

Keep in dark place,Sealed in dry,Room Temperature

pka

-1.36±0.25(Predicted)

form 

Solid

color 

Light yellow to Brown

Water Solubility 

Slightly soluble in water.

InChI

InChI=1S/C6H5FN2O2/c7-4-1-2-6(9(10)11)5(8)3-4/h1-3H,8H2

InChIKey

PEDMFCHWOVJDNW-UHFFFAOYSA-N

SMILES

C1(N)=CC(F)=CC=C1[N+]([O-])=O

CAS DataBase Reference

2369-11-1(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi,T

Risk Statements 

23/24/25-33-52/53-36/37/38

Safety Statements 

28-36/37-45-61-24/25-22

Hazard Note 

Irritant

HazardClass 

6.1

HS Code 

29214990

5-Fluoro-2-nitroaniline Usage And Synthesis

Chemical Properties

White to light yellow crystal

Uses

5-Fluoro-2-nitroaniline as a intermediate in organic synthesis.

Synthesis

2,4-Difluoronitrobenzene (15 ) was dissolved in anhydrous ethanol (10 mL) in a Schlenk flask. mmol) was dissolved in anhydrous ethanol (10 mL) in a Schlenk flask, 25% ammonia solution (10 ) was added to the mixture, and the reaction mixture was stirred at room ambient temperature. mL), the reaction mixture was stirred at room temperature, and the progress of the reaction was detected by TLC spot plate; after the reaction was finished, the precipitate was filtered off by diatomaceous earth, washed with water, and the precipitate was dried in air to obtain the target product 5-fluoro-2-nitroaniline.

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