Basic information Classification Applications Reactions Safety Supplier Related
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Bathophenanthroline

Basic information Classification Applications Reactions Safety Supplier Related

Bathophenanthroline Basic information

Product Name:
Bathophenanthroline
Synonyms:
  • BATHOPHENANTHROLINE
  • TIMTEC-BB SBB008862
  • 4,7-Diphenyl-1,1-phenanthroline
  • 4,7-DIPHENYL-1,10-PHENANTHROLINE
  • 1,10-bathophenanthroline
  • bathophenanthrolin
  • 4,7-DIPHENYL-1,10-PHENANTHRO-
  • BATHOPHENANTHROLINE R. G.
CAS:
1662-01-7
MF:
C24H16N2
MW:
332.4
EINECS:
216-767-1
Product Categories:
  • organic amine
  • oled materials
  • Analytical Chemistry
  • Chelating Reagents
  • Achiral Nitrogen
  • Py-N
  • Electroluminescence
  • Functional Materials
  • Highly Purified Reagents
  • Other Categories
  • Phenanthrolines
  • Refined Products by Sublimation
  • White crystalline powder
  • White crystalline powder
  • MOFS COFS
Mol File:
1662-01-7.mol
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Bathophenanthroline Chemical Properties

Melting point:
218-220 °C(lit.)
Boiling point:
459.52°C (rough estimate)
Density 
1.2047 (rough estimate)
refractive index 
1.7620 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in organic solvents. Slightly soluble in acidic aqueous solutions. Insoluble in neutral or alkaline solutions.
pka
4.83±0.10(Predicted)
form 
Crystalline Powder, Crystals or Crystalline Mass
color 
White to yellow to pinkish
BRN 
261048
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
DHDHJYNTEFLIHY-UHFFFAOYSA-N
CAS DataBase Reference
1662-01-7(CAS DataBase Reference)
NIST Chemistry Reference
1,10-Phenanthroline, 4,7-diphenyl-(1662-01-7)
EPA Substance Registry System
1,10-Phenanthroline, 4,7-diphenyl- (1662-01-7)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
22-24/25-36-26
WGK Germany 
3
RTECS 
SF8427000
8
TSCA 
Yes
HS Code 
29339990

MSDS

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Bathophenanthroline Usage And Synthesis

Classification

Hole-blocking layer (HBL) materials , Electron injection layer (EIL) materials, OLEDS, Organic photovoltaics, Perovskite solar cells.

Applications

BPhen is widely used as a hole-blocking or exciton-blocking layer due to its wide energy gap and high ionisation potential.
The phenanthroline unit is small, rigid, and planar, with extended π-electrons and short hopping lengths that facilitate electron mobility. The electron mobility of BPhen is about 5 × 10-4 cm2 V-1 s-1, which is about two orders of magnitude higher than that of Alq3.
When doped with lithium, BPhen:Li is an excellent electron-transport material, and is often used as an electron-injection layer to enable ohmic contact to any electrode -- without the need to consider the work function alignments.

Reactions

  1. Bidentate ligand and reagent for determination of iron.
  2. Ligand used in the copper-catalyzed protodecarboxylation of aromatic carboxylic acids. 

Chemical Properties

white to faintly yellow crystalline powder

Definition

ChEBI: A member of the class of phenanthrolines that is 1,10-phenanthroline bearing two phenyl substituents at positions 4 and 7.

BathophenanthrolineSupplier

Zhengzhou Alfachem Co., Ltd. Gold
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0371-5331-5787
Email
2853979812@qq.com;
Shanghai Uchem Inc. Gold
Tel
21-56338808-
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sales3@myuchem.com
Tianjin Derchemist Science & Technology Co., Ltd. Gold
Tel
22-58627059-
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zdcomcon@126.com
Changchun Tuo Cai Technology Co.,ltd. Gold
Tel
0431-81292405-
Email
tuocai1@tuocaitech.com;
Wuhan Zossin Technology Co., Ltd. Gold
Email
sales@zossin.com;sales@zossin.com