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AMMONIUM TETRATHIOMOLYBDATE

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AMMONIUM TETRATHIOMOLYBDATE Basic information

Product Name:
AMMONIUM TETRATHIOMOLYBDATE
Synonyms:
  • ammoniumtetrakis(sulfido)molybdate(2-)
  • ammoniumtetrasulfidomolybdate(2-)
  • ammoniumtetrathiomolybdate(2-)
  • ammoniumthiomolybdate(vi)
  • diammonium,(beta-4)-molybdate(2-tetrathioxo-
  • AMMoniuM tetrathioMolybdate, (trace Metal basis)
  • AMMoniuM tetrathioMolybdate, 99.98%, (trace Metal basis)
  • AMMoniuM tetrathioMolybdate, 99.99% 10GR
CAS:
15060-55-6
MF:
H8MoN2S4
MW:
260.28
Product Categories:
  • inorganic compound
  • Salts
  • Ammonium Salts
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Materials Science
  • Ammonium SaltsChemical Synthesis
  • Catalysis and Inorganic Chemistry
  • Metal and Ceramic Science
  • Molybdenum
  • Metal and Ceramic Science
  • 1
Mol File:
15060-55-6.mol
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AMMONIUM TETRATHIOMOLYBDATE Chemical Properties

Melting point:
>300 °C (lit.)
storage temp. 
Refrigerator (+4°C)
solubility 
Methanol (Slightly), Water (Slightly)
form 
Powder or Cyrstals
color 
White
Water Solubility 
Slightly soluble in water.
Sensitive 
Hygroscopic
Exposure limits
ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 1000 mg/m3
InChIKey
PQNOIAHNKHBLRN-UHFFFAOYSA-P
CAS DataBase Reference
15060-55-6(CAS DataBase Reference)
EPA Substance Registry System
Molybdate(2-), tetrathioxo-, diammonium, (T-4)- (15060-55-6)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
RTECS 
QA4668250
TSCA 
Yes
HS Code 
28417000

MSDS

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AMMONIUM TETRATHIOMOLYBDATE Usage And Synthesis

Chemical Properties

brown to black iridescent crystalline powder

Uses

Ring opening of aziridines leading to sulfides and disulfides.1

Uses

Ammonium tetrathiomolybdate is used as an important reagent in synthetic chemistry and as a building block in bioinorganic chemistry. It is used in the treatment of copper toxicosis in animals and in Wilson's disease. It acts as a chelator in vivo to reduce copper levels. It interferes with angiogenesis and reduces tumor growth. Further, it is used in the synthesis of heterometallic sulfide clusters stabilized with dppm [bis(diphenylphosphino)methane] ligands. It is involved in the ring opening of aziridines leading to sulfides and disulfides.

Biochem/physiol Actions

Acts as a chelator in vivo to reduce copper levels. Tetrathiomolybdate interferes with angiogenesis and reduces tumor growth. Its mechanism may involve inhibition of NF-κB and downstream cytokines.

AMMONIUM TETRATHIOMOLYBDATESupplier

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