Titanium ethoxide Chemical Properties

Melting point:

54°C

Boiling point:

150-152 °C10 mm Hg(lit.)

Density 

1.088 g/mL at 25 °C(lit.)

vapor pressure 

57.26hPa at 19.6℃

refractive index 

n20/D 1.505(lit.)

Flash point:

84 °F

storage temp. 

2-8°C

solubility 

Soluble in organic solvents.

form 

Liquid

Specific Gravity

1.107 (20℃)

color 

Pale yellow

Water Solubility 

reacts

Sensitive 

Moisture Sensitive

BRN 

3678992

Exposure limits

ACGIH: TWA 200 ppm; STEL 400 ppm
OSHA: TWA 400 ppm(980 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3)

Stability:

Stability Incompatible with strong oxidizing agents, strong acids. May decompose upon exposure to air or moisture.

InChIKey

JMXKSZRRTHPKDL-UHFFFAOYSA-N

LogP

-0.3 at 25℃

CAS DataBase Reference

3087-36-3(CAS DataBase Reference)

NIST Chemistry Reference

Ti(OEt)4(3087-36-3)

EPA Substance Registry System

Ethanol, titanium(4+) salt (3087-36-3)

Safety Information

Hazard Codes 

Xi

Risk Statements 

10-36/37/38-67

Safety Statements 

26-37/39-16

RIDADR 

UN 1993 3/PG 3

WGK Germany 

3

F 

3-10-21

TSCA 

Yes

HazardClass 

4.1

PackingGroup 

III

HS Code 

29051900

MSDS

• Language:English Provider:Ethyl titanate
• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Titanium ethoxide Usage And Synthesis

Chemical Properties

colourless liquid

Uses

Titanium(IV) ethoxide is used in organic synthesis and material science. It is involved in the synthesis of anti-perspirants and antifungal agents. Furthermore, it is used to prepare carbon films in association with silicon dioxide. It is also used as a precursor for the synthesis of Ti4+ ions titanium nanoparticles by various methods.

Uses

Titanium ethoxide is used widely as a precursor for the synthesis of Ti⁴⁺ ions titania nanoparticles by various techniques such as :

• in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
• spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
• by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.

Uses

Titanium(IV) ethoxide can be used:

• As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
• As a Ti⁴⁺ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
• As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Application

Titanium(IV) ethoxide can be used:
As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Flammability and Explosibility

Flammable

Materials Uses

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.

Titanium ethoxide(3087-36-3)Related Product Information

• Titanium
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• TITANIUM
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• THALLIUM (I) ETHOXIDE
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• Ethoxyquin
• ISOXADIFEN-ETHYL
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• Barium titanate
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