2-(Trimethylsilylmethyl)allyl acetate Chemical Properties

Boiling point:

95 °C7 mm Hg(lit.)

Density 

0.877 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.440(lit.)

Flash point:

160 °F

storage temp. 

Inert atmosphere,2-8°C

solubility 

Solubility most organic solvents.

form 

Liquid

color 

Clear colorless

Water Solubility 

reacts

BRN 

1933657

InChIKey

IKQWABMHZKGCLX-UHFFFAOYSA-N

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38-14

Safety Statements 

26-36/37/39-37/39

WGK Germany 

3

HS Code 

29319090

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich

2-(Trimethylsilylmethyl)allyl acetate Usage And Synthesis

Chemical Properties

Clear colorless liquid

Physical properties

bp 68–70°C/6.5 mmHg;60–61°C/2.5 mmHg.

Uses

2-[(Acetoxymethyl)allyl]trimethylsilane was used in the cyclopentane synthesis via Pd(0)-catalyzed reactions with 2π acceptors.

Uses

precursor for palladium trimethylenemethane cycloaddition reactions.

Preparation

commercially available but expensive. Several preparations of (1) or the precursor alcohol (2) have been reported. The simplest involves the direct silylation of methallyl alcohol (eq 1).

2-(Trimethylsilylmethyl)allyl acetate(72047-94-0)Related Product Information

• Allyl chloride
• Magnesium acetate
• Ammonium acetate
• Allyltrimethylsilane
• Allyl bromide
• Allyl glycidyl ether
• 3-Mercaptopropyltriethoxysilane
• 3-Aminopropyltrimethoxysilane
• Allyl phenoxyacetate
• Sodium triacetoxyborohydride
• TRICYCLODECENYL ACETATE
• Sodium acetate
• Butyl acetate
• Triethoxyvinylsilane
• Vinyl acetate
• 3-Chloropropyltriethoxysilane
• Benzyl acetate
• Goserelin acetate