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Phenyl 2-pyridyl ketoxime

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Phenyl 2-pyridyl ketoxime Basic information

Product Name:
Phenyl 2-pyridyl ketoxime
Synonyms:
  • 2-BENZOYLPYRIDINE KETOXIME
  • 2-Benzoylpyridine oxime
  • 2-Benzoylpyridiineketoxime
  • PPKO
  • PHENYL-ALPHA-PYRIDYL KETOXIME
  • PHENYL-A-PYRIDYL KETOXIME
  • PHENYL 2-PYRIDYL KETONE OXIME
  • PHENYL 2-PYRIDYL KETOXIME
CAS:
1826-28-4
MF:
C12H10N2O
MW:
198.22
EINECS:
217-374-8
Product Categories:
  • Heterocyclic Compounds
  • Analytical Chemistry
  • Bipyridyls, etc. (Chelating Reagents)
  • Chelating Reagents
  • C9 to C46
  • Heterocyclic Building Blocks
  • Pyridines
Mol File:
1826-28-4.mol
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Phenyl 2-pyridyl ketoxime Chemical Properties

Melting point:
154-156 °C (lit.)
storage temp. 
Store below +30°C.
form 
Crystalline Powder
color 
Slightly pink
Water Solubility 
insoluble
CAS DataBase Reference
1826-28-4(CAS DataBase Reference)
NIST Chemistry Reference
Phenyl-«alpha»-pyridyl ketoxime(1826-28-4)
EPA Substance Registry System
Methanone, phenyl-2-pyridinyl-, oxime (1826-28-4)
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Safety Information

Hazard Codes 
T,Xi
Risk Statements 
25-37/38-41-36/37/38
Safety Statements 
26-36/37/39-45-37/39
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
TSCA 
Yes
HazardClass 
6.1
HS Code 
29333990

MSDS

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Phenyl 2-pyridyl ketoxime Usage And Synthesis

Chemical Properties

Slightly pinl crystalline powder

Uses

Phenyl 2-pyridyl ketoxime was used in preparation of inverse-9-metallacrown-3, trinuclear clusters.

General Description

The complexation reaction of phenyl 2-pyridyl ketoxime with some transition and heavy metal ions Co2+, Ni2+, Zn2+, Pb2+, Fe2+, Fe3+, Cr3+ and La2+ has been studied potentiometrically. The reactions of phenyl(2-pyridyl)ketone oxime, with nickel(II) sulfate hexahydrate, in the absence of an external base, have been investigated.

Purification Methods

The E-isomer crystallises from EtOH (charcoal). It isomerizes to the Z-isomer on melting or in boiling o-xylene, and crystallises from EtOH or cyclohexanol with m 166-168o. [Beilstein 21 H 330, 21 III/IV 4120, 21/8 V 568.]

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