4-Cyanobenzoyl chloride
4-Cyanobenzoyl chloride Basic information
- Product Name:
- 4-Cyanobenzoyl chloride
- Synonyms:
-
- 4-CYANOBENZOYL CHLORIDE
- LABOTEST-BB LTBB000677
- P-CYANOBENZOYL CHLORIDE
- 4-Cyanocbenzoyl chloride
- 4-Cyanobenzoyl chloride 98%
- 4-Cyanobenzoyl chloride ,97%
- 4-cyanobenzoic chloride
- 4-Cyanobenzenecarbonyl chloride
- CAS:
- 6068-72-0
- MF:
- C8H4ClNO
- MW:
- 165.58
- EINECS:
- 228-005-5
- Product Categories:
-
- Absolute Configuration Determination (Exciton Chirality CD Method)
- Analytical Chemistry
- Benzonitriles (Building Blocks for Liquid Crystals)
- Building Blocks for Liquid Crystals
- Enantiomer Excess & Absolute Configuration Determination
- Exciton Chirality CD Method (for Hydroxyl Groups)
- Aromatic Halides (substituted)
- Functional Materials
- Acid Halides
- Carbonyl Compounds
- Organic Building Blocks
- Mol File:
- 6068-72-0.mol
4-Cyanobenzoyl chloride Chemical Properties
- Melting point:
- 68-70 °C(lit.)
- Boiling point:
- 110 °C / 2mmHg
- Density
- 1.2744 (rough estimate)
- refractive index
- 1.5430 (estimate)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Crystalline Powder
- color
- Almost white to beige
- Water Solubility
- Reacts with water.
- Sensitive
- Moisture Sensitive
- BRN
- 386729
- InChIKey
- USEDMAWWQDFMFY-UHFFFAOYSA-N
- CAS DataBase Reference
- 6068-72-0(CAS DataBase Reference)
Safety Information
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45-24/25
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- Hazard Note
- Irritant
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29269090
MSDS
- Language:English Provider:4-Cyanobenzoyl chloride
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
4-Cyanobenzoyl chloride Usage And Synthesis
Chemical Properties
almost white to beige crystalline powder
Uses
4-Cyanobenzoyl chloride has been used in the synthesis of new liquid crystalline heteroaromatic compounds containing the five-membered isoxazole, tetrazole and 1,2,4-oxadiazole rings. It has been used in the synthesis of substituted benzoate esters and to study their excited-state behavior.
Definition
ChEBI: 4-cyanobenzoyl chloride is an acyl chloride consisting of benzoyl chloride in which the hydrogen at position 4 is replaced by a cyano group. It is a nitrile, a member of benzenes and an acyl chloride. It is functionally related to a benzoyl chloride.
General Description
4-Cyanobenzoyl chloride participates in the benzylamine acylation of Argopore MB-CHO resin in the presence of pyridine and catalyst. It reacts with 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinoxyl (4-hydroxy-TEMPO) in pyridine under nitrogen atmosphere to form 4-cyanobenzoyl-TEMPO.
Purification Methods
If the IR shows the presence of OH, then treat it with SOCl2 boil for 1hour, evaporate and distil it in a vacuum. The distillate solidifies and can be recrystallised from pet ether. It is moisture sensitive and an IRRITANT. [Ashley et al. J Chem Soc 103 1942, Fison et al. J Org Chem 16 648 1951,[Beilstein 9 III 4255, 14 IV 3327.]
4-Cyanobenzoyl chloride Preparation Products And Raw materials
Raw materials
4-Cyanobenzoyl chlorideSupplier
- Tel
- 028-88469284 18000562381
- rzbtsj@163.com
- Tel
- 0411-88165951 13601035838
- marketing@qi-chem.com
- Tel
- 010-88018188-305 13601004222
- maxma@bj-odyssey.com
- Tel
- 15600986547
- jack@bj-odyssey.com
- Tel
- +86-0631-7336369 +86-13326315369
- master@keshengchem.com
4-Cyanobenzoyl chloride(6068-72-0)Related Product Information
- alpha,alpha,alpha-Trifluoro-o-toluoyl chloride
- Sodium chloride
- Benzoyl chloride
- 4-(Chloromethyl)benzoyl chloride
- 2-Fluorobenzoyl chloride
- Ferric chloride
- Choline chloride
- Ammonium chloride
- Sulfuryl chloride
- o-Toluoyl chloride
- 2,4,6-Trimethylbenzoyl chloride
- Potassium chloride
- Calcium chloride
- ETHYL 2-CYANOACRYLATE
- p-Toluoyl chloride
- 4-Cyanobenzoic acid
- Polyvinyl chloride
- 4-tert-Butylbenzoyl chloride