1,2-Diphenylethane
1,2-Diphenylethane Basic information
- Product Name:
- 1,2-Diphenylethane
- Synonyms:
-
- Bibenzyl,1,2-Diphenylethane, Dibenzyl
- Bibenzyl s-Diphenylethane
- 1,1'-Ethane-1,2-diyldibenzene
- Bibenzyl, 99% 100GR
- Bibenzyl, 99% 25GR
- Bibenzyl, 99% 5GR
- ethane,1,2-diphenyl-
- sym-Diphenylethane
- CAS:
- 103-29-7
- MF:
- C14H14
- MW:
- 182.26
- EINECS:
- 203-096-4
- Product Categories:
-
- Pharmaceutical Intermediates
- Arenes
- Building Blocks
- Chemical Synthesis
- Organic Building Blocks
- Mol File:
- 103-29-7.mol
1,2-Diphenylethane Chemical Properties
- Melting point:
- 50-53 °C(lit.)
- Boiling point:
- 284 °C(lit.)
- Density
- 1.014 g/mL at 25 °C(lit.)
- refractive index
- 1.5704
- Flash point:
- >230 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Soluble in ether, chloroform
- form
- Crystalline Powder
- Specific Gravity
- 1.014
- color
- White to light yellow
- Water Solubility
- PRACTICALLY INSOLUBLE
- Merck
- 14,1198
- BRN
- 508068
- Dielectric constant
- 2.4(43℃)
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- LogP
- 4.790
- CAS DataBase Reference
- 103-29-7(CAS DataBase Reference)
- NIST Chemistry Reference
- Bibenzyl(103-29-7)
- EPA Substance Registry System
- Bibenzyl (103-29-7)
Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36
- Safety Statements
- 22-24/25-182.26
- WGK Germany
- 2
- RTECS
- DT4375000
- Autoignition Temperature
- 896 °F
- Hazard Note
- Irritant
- TSCA
- Yes
- HS Code
- 29029090
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
1,2-Diphenylethane Usage And Synthesis
Chemical Properties
white to light yellow crystal powder. soluble in chloroform, ether, carbon disulfide and amyl acetate, soluble in alcohol, almost insoluble in water. It reacts with chromium trioxide or permanganic acid to generate benzoic acid.
Uses
1,2-Diphenylethane is used as solvent for nitro fibre and in synthesis of other organic chemical products.
Preparation
1,2-Diphenylethane is synthesized by the action of benzyl chloride with sodium metal. Or from the reaction of benzyl chloride in the presence of copper, or from the hydrogenation of benzoin in the presence of nickel.
Definition
ChEBI: 1,2-dihydrostilbene is a diphenylethane that is the 1,2-dihydro derivative of stilbene.
Synthesis Reference(s)
Chemical and Pharmaceutical Bulletin, 36, p. 1529, 1988 DOI: 10.1248/cpb.36.1529
Journal of the American Chemical Society, 81, p. 1243, 1959 DOI: 10.1021/ja01514a057
Purification Methods
Crystallise bibenzyl from hexane, MeOH, or 95% EtOH. It has also been sublimed under vacuum, and further purified by percolation through columns of silica gel and activated alumina. [Beilstein 5 IV 1868.]
1,2-Diphenylethane Preparation Products And Raw materials
Raw materials
Preparation Products
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1,2-Diphenylethane(103-29-7)Related Product Information
- Decabromodiphenyl Ethane
- Biphenyl-4,4'-dicarboxylic acid
- 3-Biphenylcarboxylic acid
- 2-BIPHENYLBORONIC ACID
- 4-Biphenylboronic acid
- Phenanthrenequinone
- Dibenzosuberone
- 2-Bibenzylcarboxylic acid
- MESO-1,2-DIBROMO-1,2-DIPHENYLETHANE,1,2-DIBROMO-1,2-DIPHENYLETHANE,(1R,2S)-1,2-Dibromo-1,2-diphenylethane
- Benzil
- DIBENZOSUBERYL CHLORIDE
- 2-Phenylacetophenone
- DIPHENYLGLYOXIME
- 4,4'-DIBROMOBENZIL
- DESYL CHLORIDE
- (1S,2S)-N-Methylsulfonyl-1,2-diphenylethanediamine, 98+%
- 2,2-Dimethoxy-1,2-diphenylethane-1-on
- 1-AMINO-2,2-DIPHENYLETHANE