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1,2-Diphenylethane

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1,2-Diphenylethane Basic information

Product Name:
1,2-Diphenylethane
Synonyms:
  • Bibenzyl,1,2-Diphenylethane, Dibenzyl
  • Bibenzyl s-Diphenylethane
  • 1,1'-Ethane-1,2-diyldibenzene
  • Bibenzyl, 99% 100GR
  • Bibenzyl, 99% 25GR
  • Bibenzyl, 99% 5GR
  • ethane,1,2-diphenyl-
  • sym-Diphenylethane
CAS:
103-29-7
MF:
C14H14
MW:
182.26
EINECS:
203-096-4
Product Categories:
  • Pharmaceutical Intermediates
  • Arenes
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
Mol File:
103-29-7.mol
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1,2-Diphenylethane Chemical Properties

Melting point:
50-53 °C(lit.)
Boiling point:
284 °C(lit.)
Density 
1.014 g/mL at 25 °C(lit.)
refractive index 
1.5704
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in ether, chloroform
form 
Crystalline Powder
Specific Gravity
1.014
color 
White to light yellow
Water Solubility 
PRACTICALLY INSOLUBLE
Merck 
14,1198
BRN 
508068
Dielectric constant
2.4(43℃)
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
LogP
4.790
CAS DataBase Reference
103-29-7(CAS DataBase Reference)
NIST Chemistry Reference
Bibenzyl(103-29-7)
EPA Substance Registry System
Bibenzyl (103-29-7)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36
Safety Statements 
22-24/25-182.26
WGK Germany 
2
RTECS 
DT4375000
Autoignition Temperature
896 °F
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29029090

MSDS

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1,2-Diphenylethane Usage And Synthesis

Chemical Properties

white to light yellow crystal powder. soluble in chloroform, ether, carbon disulfide and amyl acetate, soluble in alcohol, almost insoluble in water. It reacts with chromium trioxide or permanganic acid to generate benzoic acid.

Uses

1,2-Diphenylethane is used as solvent for nitro fibre and in synthesis of other organic chemical products.

Preparation

1,2-Diphenylethane is synthesized by the action of benzyl chloride with sodium metal. Or from the reaction of benzyl chloride in the presence of copper, or from the hydrogenation of benzoin in the presence of nickel.

Definition

ChEBI: 1,2-dihydrostilbene is a diphenylethane that is the 1,2-dihydro derivative of stilbene.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 36, p. 1529, 1988 DOI: 10.1248/cpb.36.1529
Journal of the American Chemical Society, 81, p. 1243, 1959 DOI: 10.1021/ja01514a057

Purification Methods

Crystallise bibenzyl from hexane, MeOH, or 95% EtOH. It has also been sublimed under vacuum, and further purified by percolation through columns of silica gel and activated alumina. [Beilstein 5 IV 1868.]

1,2-Diphenylethane Preparation Products And Raw materials

Raw materials

Preparation Products

1,2-DiphenylethaneSupplier

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