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2-BIPHENYLBORONIC ACID

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2-BIPHENYLBORONIC ACID Basic information

Product Name:
2-BIPHENYLBORONIC ACID
Synonyms:
  • 2-Boronobiphenyl, 2-Phenylbenzeneboronic acid
  • 2-Biphenylboronic Acid (contains varying aMounts of Anhydride)
  • 2-Biphenylboronic Acid 
  • TIMTEC-BB SBB005895
  • Boronic acid, B-[1,1'-biphenyl]-2-yl-
  • 2-Biphenylboronic acid (2-Phenylphenyl)boranediol
  • 2-Biphenylboronic acid, >=98%
  • BIPHENYL-2-BORONIC ACID
CAS:
4688-76-0
MF:
C12H11BO2
MW:
198.03
EINECS:
670-315-1
Product Categories:
  • Boronic Acids & Esters
  • Boronic acid
  • Boronic Acids & Esters
  • Ring Systems
  • Aryl
  • Boronic Acids
  • blocks
  • BoronicAcids
  • Boronic Acids and Derivatives
Mol File:
4688-76-0.mol
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2-BIPHENYLBORONIC ACID Chemical Properties

Melting point:
167-172 °C (lit.)
Boiling point:
404.0±38.0 °C(Predicted)
Density 
1.18
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly, Sonicated)
pka
8.50±0.58(Predicted)
form 
Powder or Low Melting Solid
color 
White to yellow
Water Solubility 
Insoluble in water.
λmax
250nm(CH2Cl2)(lit.)
BRN 
3031806
InChI
InChI=1S/C12H11BO2/c14-13(15)12-9-5-4-8-11(12)10-6-2-1-3-7-10/h1-9,14-15H
InChIKey
HYCYKHYFIWHGEX-UHFFFAOYSA-N
SMILES
B(C1=CC=CC=C1C1=CC=CC=C1)(O)O
CAS DataBase Reference
4688-76-0(CAS DataBase Reference)
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Safety Information

Hazard Codes 
C,Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36-60-37
WGK Germany 
3
Hazard Note 
Corrosive
HazardClass 
IRRITANT
HS Code 
29310095

MSDS

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2-BIPHENYLBORONIC ACID Usage And Synthesis

Chemical Properties

Off-white powder

Uses

suzuki reaction

Uses

Reactant involved in:

  • Suzuki-Miyaura cross-coupling reactions with arylhalides, dibromovinyl precursors, alkenyl tosylates and mesylates, and quinoline carboxylates
  • Intramolecular Friedel-Crafts alkylation for synthesis of chiral tetralins
  • Hydroxylation to phenols
  • Oxidative coupling iwth alkynes

2-BIPHENYLBORONIC ACIDSupplier

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