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4-Bromostyrene

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4-Bromostyrene Basic information

Product Name:
4-Bromostyrene
Synonyms:
  • Benzene, 1-bromo-4-ethenyl-
  • benzene,1-bromo-4-ethenyl-
  • Styrene, p-bromo-
  • styrene,p-bromo-
  • 4-BROMOSTYRENE
  • BROMOSTYRENE-4
  • 4-BROMOSTYRENE, STAB.
  • 4-BROMOSTYRENE (STABILISED)
CAS:
2039-82-9
MF:
C8H7Br
MW:
183.05
EINECS:
218-022-6
Product Categories:
  • Polymer Science
  • Styrene and Functionalized Styrene Monomers
  • Styrenes
  • Monomers
  • Chloromethy styrene
Mol File:
2039-82-9.mol
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4-Bromostyrene Chemical Properties

Melting point:
4.5 °C
Boiling point:
89 °C16 mm Hg(lit.)
Density 
1.40 g/mL at 20 °C
refractive index 
n20/D 1.594(lit.)
Flash point:
168 °F
storage temp. 
-20°C
solubility 
Miscible with ethanol, ether and benzene.
form 
Liquid
color 
light greenish-yellow
BRN 
1634204
InChIKey
WGGLDBIZIQMEGH-UHFFFAOYSA-N
CAS DataBase Reference
2039-82-9(CAS DataBase Reference)
NIST Chemistry Reference
4-BrC6H4CH=CH2(2039-82-9)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/38-36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
8
Hazard Note 
Irritant/Keep Cold
HS Code 
29036990

MSDS

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4-Bromostyrene Usage And Synthesis

Chemical Properties

clear slightly yellow to yellow liquid

Uses

4-Bromostyrene is widely utilized in the synthesis of nitroolefins by alkene cross-metathesis. It plays an important role in the Heck reaction to the synthesis of poly(1,4-phenylenevinylene). It is employed in the structure activity relationships (SAR) study of the chemical and biochemical properties of the vinyl group of styrene. It is also used to investigate the photochemical growth of Br-terminated self-assembled monolayers. It is also involved in the synthesis of silsesquioxanes.

General Description

4-Bromostyrene is a para-halogenated styrene derivative. The proton spectra of 4-bromostyrene exhibits dipolar couplings consistent with planar ground state structures, only if the torsional motion of lowest frequency occurs at about 80cm-1. It undergoes Heck reaction with 2-bromo-6-methoxynaphthalene in the presence of sodium acetate and Hermann′s catalyst in N,N-dimethylacetamide to afford diarylethene.

Purification Methods

It polymerises above 75o in the presence of benzoyl peroxide. To purify, if it has not gone to a solid resin, dissolve it in Et2O, dry (MgSO4) and add ca 0.1g of 4-tertbutylcatechol (polymerisation inhibitor) per 100g of bromostyrene. Filter, evaporate this under reduced pressure (use as high a vacuum as possible) and distil the residue. Store it in dark bottles in the presence of the inhibitor (at above concentration). [Overberger & Saunders Org Synth Coll Vol III 204 1955, Beilstein 5 IV 1349.]

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