CHLOROMETHYL PHENYL SULFIDE Chemical Properties

Boiling point:

66 °C/0.2 mmHg (lit.)

Density 

1.184 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.594(lit.)

Flash point:

214 °F

storage temp. 

2-8°C

form 

Liquid

color 

Clear colorless to pale yellow

Sensitive 

Stench

BRN 

1617369

InChIKey

LLSMWLJPWFSMCP-UHFFFAOYSA-N

CAS DataBase Reference

7205-91-6(CAS DataBase Reference)

Safety Information

Safety Statements 

23-24/25

RIDADR 

UN 3334

WGK Germany 

3

F 

10-13

Hazard Note 

Stench

HazardClass 

4.1

PackingGroup 

III

HS Code 

29309099

MSDS

• Language:English Provider:SigmaAldrich

CHLOROMETHYL PHENYL SULFIDE Usage And Synthesis

Uses

Reagent for the high-yield thiomethylation of O-silylated lactone and ester enolates in the synthesis of α-methylene lactones and esters.1

Uses

Reagent for the high-yield thiomethylation of O-silylated lactone and ester enolates in the synthesis of α-methylene lactones and esters.

Purification Methods

Dissolve the sulfide in CH2Cl2 or CCl4 and dry it (CaCl2), or pass it through a tube of CaCl2 and distil it using a fractionating column. Harmful vapours. It gives the sulfone [7205-98-3] (b 130o/1mm and m 53o from EtOH) [Beilstein 6 IV 1507] on oxidation with permonophthalic acid. [B.hme et al. Justus Liebigs Ann Chem 563 54 64 1949.] [Beilstein 6 III 1002.]

CHLOROMETHYL PHENYL SULFIDE(7205-91-6)Related Product Information

• Chlorosulfonyl isocyanate
• 1-BENZYL-3-CHLORO-3-[(4-CHLOROPHENYL)SULFANYL]DIHYDRO-1H-PYRROLE-2,5-DIONE
• 3,5-BIS(TRIFLUOROMETHYL)PHENYL CHLOROMETHYL SULFONE
• Thiazolo[4,5-h]isoquinoline, 2-chloro- (9CI)
• CHLOROMETHYL PHENYL SULFOXIDE
• 1-[(1-CHLORO-2,2,2-TRIFLUOROETHYL)THIO]-4-METHYLBENZENE
• 3-(3-chloro-4-(chlorodifluoromethyl)thiophenyl)-1,1-dimethylurea
• 2-[(1-CHLORO-2,2,2-TRIFLUOROETHYL)THIO]ANILINE
• [(1-CHLORO-4-PHENYLBUTA-1,3-DIENYL)SULFINYL]BENZENE
• CHLOROMETHYL 4-CHLOROPHENYL SULFIDE
• CHLOROMETHYL P-TOLYL SULFIDE
• PHENYL CHLOROTHIOFORMATE
• 4-[2-CHLORO-2-(PHENYLSULFONYL)ETHYL]-1,4-OXAZINAN-4-IUM CHLORIDE
• P-CHLOROPHENYL TRICHLOROMETHYL SULFIDE
• SPECS AK-823/41252283
• 2-(4-TRICHLOROMETHYLTHIOPHENOXY)-5-NITROTOLUENE
• CHLOROMETHYL PHENYL SULFONE
• CHLOROMETHYL PHENYL SULFIDE