2-(Morpholinothio)benzothiazole Chemical Properties

Melting point:

78-80°C

Boiling point:

413.1±55.0 °C(Predicted)

Density 

1.34-1.40

vapor pressure 

0.001Pa at 25℃

refractive index 

1.5650 (estimate)

storage temp. 

Sealed in dry,2-8°C

solubility 

Acetone (Slightly, Heated, Sonicated), Chloroform (Slightly)

pka

1.05±0.10(Predicted)

form 

Solid

color 

White to Pale Yellow

Odor

buff to brn. flakes, sweet odor

LogP

3.4 at 25℃ and pH7

Dissociation constant

-6.82-2.65 at 25℃

CAS DataBase Reference

102-77-2(CAS DataBase Reference)

NIST Chemistry Reference

Morpholine, 4-(2-benzothiazolylthio)-(102-77-2)

EPA Substance Registry System

Benzothiazole, 2-(4-morpholinylthio)- (102-77-2)

Safety Information

Hazard Codes 

Xi,N

Risk Statements 

22-51/53-43-36/38

Safety Statements 

20/21-36-61-37-26-24-24/25

RIDADR 

3077

RTECS 

DL5950000

HazardClass 

9

PackingGroup 

III

HS Code 

29342000

Hazardous Substances Data

102-77-2(Hazardous Substances Data)

Toxicity

LD50 orl-rat: 1980 mg/kg IPSTB3 3,93,76

2-(Morpholinothio)benzothiazole Usage And Synthesis

Description

This rubber vulcanization accelerator is used as a chemical in the rubber industry, especially in the production of synthetic rubber articles. Is contained in the "mercapto mix". As a corrosion inhibitor, it can be found in cutting fluids or in releasing fluids in the pottery industry. It induces mainly delayed-type hypersensitivity, but a case of immediate-type hypersensitivity was reported in a dental assistant.

Chemical Properties

Buff to brown flakes; sweet odor. Insoluble in water; solublein benzene, acetone, methanol.

Uses

Delayed-action vulcanization accelerator.

Contact allergens

This rubber vulcanization accelerator belongs to the mercaptobenzothiazole-sulfenamide group. It is used as a chemical in the rubber industry, especially in the production of synthetic rubber articles. It is contained in “mercapto mix.” As a corrosion inhibitor, it can be found in cutting fluids or in releasing fluids in the pottery industry. It induces mainly delayed-type hypersensitivity, but a case of immediate-type hypersensitivity was reported in a dental assistant.

Safety Profile

Poison by intraperitoneal route.Moderately toxic by ingestion. Questionable carcinogenwith experimental neoplastigenic data. Experimentalteratogenic effects. An eye irritant. Mutation datareported. When heated to decomposition it emits very toxic fum

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