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3-Methoxycarbonylphenylboronic acid

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3-Methoxycarbonylphenylboronic acid Basic information

Product Name:
3-Methoxycarbonylphenylboronic acid
Synonyms:
  • METHYL 3-BORONOBENZOATE
  • 3-METHOXYCARBONYLPHENYLBORONIC ACID
  • 3-(METHOXYCARBONYL)BENZENEBORONIC ACID
  • AKOS BRN-0125
  • M-(METHOXYCARBONYL)PHENYLBORONIC ACID
  • 3-METHOXYCARBONYLPHENYLBARONIC ACID
  • 3-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
  • 3-Methoxycarbonylphenylboronic acid,97%
CAS:
99769-19-4
MF:
C8H9BO4
MW:
179.97
Product Categories:
  • Aromatics
  • Boron Derivatives
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • Boronate Ester
  • Potassium Trifluoroborate
  • Acids and Derivatives
  • Boron, Nitrile, Thio,& TM-Cpds
  • Boronic acids
  • Aryl
  • Ester
  • Organoborons
  • B (Classes of Boron Compounds)
  • Boronic acid
  • blocks
  • BoronicAcids
  • Carboxes
  • CHIRAL CHEMICALS
Mol File:
99769-19-4.mol
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3-Methoxycarbonylphenylboronic acid Chemical Properties

Melting point:
205-208 °C(lit.)
Boiling point:
359.9±44.0 °C(Predicted)
Density 
1.25±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
7.74±0.10(Predicted)
form 
Powder
color 
White to off-white
Water Solubility 
Reacts with water.
InChI
InChI=1S/C8H9BO4/c1-13-8(10)6-3-2-4-7(5-6)9(11)12/h2-5,11-12H,1H3
InChIKey
ALTLCJHSJMGSLT-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=CC(B(O)O)=C1
CAS DataBase Reference
99769-19-4(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-36
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29319090

MSDS

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3-Methoxycarbonylphenylboronic acid Usage And Synthesis

Chemical Properties

White to light yellow crystal powde

Uses

Reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration, cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. Reagent used in Preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6, chromenones and their bradykinin B1 antagonistic active, Pt nanoparticles at Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injecti, salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.

Uses

3-Methoxycarbonylphenylboronic acid can be used in the preparation of substituted pyrazolylpyrimidinamine derivative for use as protein kinase inhibitors and suzuki reaction.

3-Methoxycarbonylphenylboronic acid Preparation Products And Raw materials

Raw materials

3-Methoxycarbonylphenylboronic acidSupplier

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