Bis(tri-tert-butylphosphine)palladium(0)
Bis(tri-tert-butylphosphine)palladium(0) Basic information
- Product Name:
- Bis(tri-tert-butylphosphine)palladium(0)
- Synonyms:
-
- BIS(TRI-T-BUTYLPHOSPHINE)PALLADIUM(0)
- BIS(TRI-TERT-BUTYLPHOSPHINE)PALLADIUM
- BIS(TRI-TERT-BUTYLPHOSPHINE)PALLADIUM (0)
- Bis(tri-t-butylphosphine)palladium(0),98%
- Bis(tri-t-butyl)phosphino Pd0
- Bis(tri-t-butylphosphine)palladium,
- Bis(tri-tert-butylphosphin)palladium(0)
- Bis(tri-tert-butylphosphine)palladium (0) Reasonably stable for packaging and transfer.
- CAS:
- 53199-31-8
- MF:
- C24H56P2Pd
- MW:
- 513.08
- EINECS:
- 640-284-9
- Product Categories:
-
- chemical reaction,pharm,electronic,materials
- organometallic phosphine complex
- Catalysis and Inorganic Chemistry
- Homogeneous Pd Catalysts
- Palladium
- Pd (Palladium) Compounds
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Homogeneous Catalysts
- Metal Complexes
- Pd
- Mol File:
- 53199-31-8.mol
Bis(tri-tert-butylphosphine)palladium(0) Chemical Properties
- Melting point:
- >300 °C
- storage temp.
- -20°C
- form
- Crystals
- color
- Off-white to orange-brown
- Water Solubility
- insoluble
- Sensitive
- Light, Air & Moisture Sensitive
- InChI
- InChI=1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;/q;;-2/p+2
- InChIKey
- XULQKWNZCKOVSU-UHFFFAOYSA-P
- SMILES
- P(C(C)(C)C)(C(C)(C)C)(C(C)(C)C)[Pd]P(C(C)(C)C)(C(C)(C)C)C(C)(C)C
- CAS DataBase Reference
- 53199-31-8(CAS DataBase Reference)
Bis(tri-tert-butylphosphine)palladium(0) Usage And Synthesis
Reaction
- Introduced as an easier to handle Pd/P(t-Bu)3-based catalyst for the Negishi cross-coupling of aryl/vinyl chlorides.
- A versatile catalyst for the cross-coupling of aryl and vinyl chlorides.
- Catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases.
- Useful catalyst for the cross-coupling of heteroaromatic carboxylic acids.
- Pd-catalyzed Newnan-Kwart rearrangement of O-aryl thiocarbamates.
- Cross-coupling of silanolates and halides.
- Elimination/isomerization of enol triflates derived from β-ketoesters.
Chemical Properties
Off white crystalline solid
Uses
Catalyst for Suzuki coupling on a multisubstituted sp 3 -carbon (eq. 1) Catalyst for Stille coupling reaction of aryl chlorides 2 (eq. 2) Catalyst for Negishi coupling reaction 3 (eq. 3) Catalyst for Heck coupling to form tetrasubstituted olefins 4 (eq. 4) Catalyst for Buchwald-Hartwig amination of aryl halide 5 (eq. 5) Catalyst for carbonylation of aryl halides with carbamoylsilanes 6 (eq. 6) t -Bu 3 P) 2 catalyst.
Uses
Bis(tri-tert-butylphosphine)palladium(0) is used in Coupling reactions, Heck couplings. It acts as a palladium catalyst for reductive carbonylation.
General Description
This product has been enhanced for catalytic efficiency.
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
Bis(tri-tert-butylphosphine)palladium(0) Preparation Products And Raw materials
Raw materials
Bis(tri-tert-butylphosphine)palladium(0)Supplier
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Bis(tri-tert-butylphosphine)palladium(0)(53199-31-8)Related Product Information
- Tri-tert-butylphosphine
- T-BUTYLPHOSPHINE
- Diphenylphosphine
- tert-Butyldimethylsilyl chloride
- tert-Butanol
- Palladium (II) Acetate
- Dibutyltin dilaurate
- Tributylphosphine
- Tetrakis(triphenylphosphine)platinum
- Tris(triphenylphosphine)ruthenium(II) chloride
- Chlorodiphenylphosphine
- Palladium
- Tetrakis(triphenylphosphine)palladium
- tert-Butylchlorodiphenylsilane
- Allylpalladium(II) Chloride Dimer
- TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II)
- Bis(acetonitrile)dichloropalladium(II)
- dichlorobis(di-tert-butylphenylphosphine)palladium(II)