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DL-2-AMINO-4-PENTENOIC ACID

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DL-2-AMINO-4-PENTENOIC ACID Basic information

Product Name:
DL-2-AMINO-4-PENTENOIC ACID
Synonyms:
  • DL-2-aminopent-4-enoic acid
  • DL-Allylglycine 2-Amino-4-pentenoic acid
  • ALLYLGLYCINE[ALLYGLY]
  • (+/-)-2-AMINO-4-PENTENOIC ACID BIOCHEMIKA
  • 2-Amino-4-pentanoic acid
  • 2-Aminopent-4-enoic acid
  • rac-(2R*)-2-Amino-4-pentenoic acid
  • rac-(R*)-2-Allylglycine
CAS:
7685-44-1
MF:
C5H9NO2
MW:
115.13
EINECS:
231-689-8
Product Categories:
  • Pyridines
Mol File:
7685-44-1.mol
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DL-2-AMINO-4-PENTENOIC ACID Chemical Properties

Melting point:
258-260 °C(lit.)
Boiling point:
215.41°C (rough estimate)
Density 
1.1808 (rough estimate)
refractive index 
1.4538 (estimate)
storage temp. 
-20°C
Water Solubility 
Soluble in water
form 
Crystalline Powder
pka
2.22±0.10(Predicted)
color 
White
BRN 
1748645
CAS DataBase Reference
7685-44-1(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38-43
Safety Statements 
26-36/37-36
WGK Germany 
3
HS Code 
29224999

MSDS

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DL-2-AMINO-4-PENTENOIC ACID Usage And Synthesis

Chemical Properties

white crystalline powder

Biochem/physiol Actions

DL-2-Allylglycine is a racemic mixture of L- and D-allylglycine. D-allylglycine is the enantiomer of L-allylglycine, a glutamate decarboxylase (GAD) inhibitor used in GABA research. D-allylglycine may be used as a control supplement versus L-allylglycine in GABA research. D-allylglycine is used in the organic synthesis of cyclic opioid peptide agonists and antagonists.

Purification Methods

Dissolve it in absolute EtOH and precipitate it with pyridine, then recrystallise it from aqueous EtOH [RF on paper in BuOH/EtOH/NH3/H2O (4:4:1:1:) is 0.37]. The hydrobromide has m 136-140o (from EtOAc) and the phenylureido derivative has m 159-161o. [Schgl Monatsh Chem 89 377 1958, Beilstein 4 IV 2852.]

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