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DIETHYL DIALLYLMALONATE

Basic information Safety Supplier Related

DIETHYL DIALLYLMALONATE Basic information

Product Name:
DIETHYL DIALLYLMALONATE
Synonyms:
  • Diethyl 2,2-diallylmalonate , Tech.
  • 2,2-(Diallyl)malonic acid diethyl ester
  • Di-2-propenylpropanedioic acid diethyl ester
  • Diethyl diallylmalonate 98%
  • Diethyl-2-allyl-2-butenylmalonate
  • Malonic acid, diallyl-, diethyl ester
  • Propanedioic acid, di-2-propenyl-, diethyl ester
  • DIALLYLMALONIC ACID DIETHYL ESTER
CAS:
3195-24-2
MF:
C13H20O4
MW:
240.3
EINECS:
221-696-4
Product Categories:
  • monomer
  • Aliphatics
  • Esters
  • C12 to C63
  • Carbonyl Compounds
Mol File:
3195-24-2.mol
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DIETHYL DIALLYLMALONATE Chemical Properties

Boiling point:
128-130 °C/12 mmHg (lit.)
Density 
0.994 g/mL at 25 °C (lit.)
vapor pressure 
4.266Pa at 25℃
refractive index 
n20/D 1.446(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform, DMSO, Methanol
form 
Oil
color 
Clear Colourless
Water Solubility 
Sparingly Soluble in water. (0.72 g/L) (25°C)
BRN 
1790529
LogP
3.46
CAS DataBase Reference
3195-24-2(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
2917198090

MSDS

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DIETHYL DIALLYLMALONATE Usage And Synthesis

Uses

Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

Definition

ChEBI: Diethyl diallylmalonate is a fatty acid ester.

General Description

Low catalyst loading in ring-closing metathesis reaction of diethyl diallylmalonate has been reported. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

DIETHYL DIALLYLMALONATESupplier

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