1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE- Chemical Properties

Boiling point:

84-87 °C/4 mmHg (lit.)

Density 

1.315 g/mL at 25 °C (lit.)

Flash point:

160 °F

storage temp. 

2-8°C

form 

Liquid

color 

Colorless to yellow

Safety Information

RIDADR 

NA 1993 / PGIII

WGK Germany 

3

HS Code 

2904990090

1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE- Usage And Synthesis

Uses

Cyclohex-1-en-1-yl Trifluoromethanesulfonate is used a reactant in the regioselective preparation of phenylpyrrolidines via C-H functionalization of amines with aryl halides.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 277, 1986 DOI: 10.1021/jo00352a039

General Description

1-Cyclohexenyl trifluoromethanesulfonate, also known as 1-cyclohexenyl triflate, is a cyclohexenyl sulfonate. Its trifluoromethylation reaction in the presence of different monodentate biaryl phosphine ligands has been investigated. The asymmetric Heck reaction of 1-cyclohexenyl trifluoromethanesulfonate using palladium complexes of phosphine oxazoline ligand has been studied.

1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-(28075-50-5)Related Product Information

• METHANE
• Methanesulfonic acid, trifluoro-, cyclopropyl ester
• CALCIUM TRIFLUOROMETHANESULFONATE
• Nickel(II) Trifluoromethanesulfonate
• Lanthanum trifluoromethanesulfonate
• Aluminum trifluoromethanesulfonate
• Thulium(III) Trifluoromethanesulfonate
• CUPROUS TRIFLUOROMETHANESULFONATE TOLUENE COMPLEX
• Trifluoromethanesulfonamide
• NEODYMIUM(III) TRIFLUOROMETHANESULFONATE
• TIN(II) TRIFLUOROMETHANESULFONATE
• tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate hemihydrate
• TERBIUM (III) TRIFLUOROMETHANESULFONATE
• IRON(II) TRIFLUOROMETHANESULFONATE
• ERBIUM (III) TRIFLUOROMETHANESULFONATE
• Potassium trifluoromethanesulfonate
• YTTERBIUM(III) TRIFLATE HYDRATE, 99.90%
• P-TOLYL TRIFLATE