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4-BENZOYLOXY-TEMPO

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4-BENZOYLOXY-TEMPO Basic information

Product Name:
4-BENZOYLOXY-TEMPO
Synonyms:
  • 4-HYDROXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL BENZOATE
  • 4-HYDROXY-TEMPO BENZOATE
  • 4-HYDROXY-TEMPO BENZOATE, FREE RADICAL
  • 4-BENZOYLOXY-TEMPO
  • 4-BENZOYLOXY-TEMPO FREE RADICAL
  • 4-BENZOYLOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL
  • 4-Benzoyloxy-2,2,6,6-tetramethylpiperidinyloxy, free radical~4-Hydroxy-TEMPO benzoate, free radical
  • 4-Benzyloxy-TEMPO,freeradical
CAS:
3225-26-1
MF:
C16H22NO3*
MW:
276.35
EINECS:
807-702-3
Product Categories:
  • Analytical Chemistry
  • ESR Spectrometry
  • Oxidation
  • Spin Labels
  • Synthetic Organic Chemistry
Mol File:
3225-26-1.mol
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4-BENZOYLOXY-TEMPO Chemical Properties

Melting point:
99-101 °C (lit.)
Density 
0.001g/cm3 at 20℃
vapor pressure 
11.5Pa at 20℃
form 
Crystalline
color 
Light yellow to Brown
BRN 
1431263
Stability:
Stable. Incompatible with strong oxidizing agents.
LogP
3.13 at 20℃ and pH7.88
CAS DataBase Reference
3225-26-1(CAS DataBase Reference)
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29329990

MSDS

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4-BENZOYLOXY-TEMPO Usage And Synthesis

Chemical Properties

orange crystalline powder

Uses

4-Hydroxy-TEMPO Benzoate, Free Radical is a recycling catalyst in a hypochlorite/bromite-nitroxide oxidizing system for conversion of alcohols to aldehydes, ketones, and carboxylic acids. It circumvents the need to use a catalytic or stoichiometric heavy metal oxidant.

Uses

Recycling catalyst in hypochlorite/bromite-nitroxide oxidizing system for conversion of alcohols to aldehydes, ketones, and carboxylic acids. It circumvents the need to use a catalytic or stoichiometric heavy metal oxidant.

Definition

ChEBI: 4-hydroxy-TEMPO benzoate is a member of the class of piperidines that is TEMPO carrying a benzoyloxy group at position 4. It has a role as a radical scavenger and a spin probe. It is a member of aminoxyls, a member of piperidines and a benzoate ester. It is functionally related to a 4-hydroxy-TEMPO.

General Description

4-Hydroxy-TEMPO benzoate is a 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivative.

4-BENZOYLOXY-TEMPOSupplier

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