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2-METHYL-6-NITROBENZOIC ACID

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2-METHYL-6-NITROBENZOIC ACID Basic information

Product Name:
2-METHYL-6-NITROBENZOIC ACID
Synonyms:
  • 6-NITRO-O-TOLUIC ACID
  • 2-NITRO-6-METHYLBENZOIC ACID
  • 2-METHYL-6-NITROBENZOIC ACID
  • RARECHEM AL BO 0232
  • Benzoic acid, 2-methyl-6-nitro-
  • 2-METHYL-6-NITROBENZOIC ACID / 6-NITRO-O-TOLUIC ACID
  • 6-Nitro-o-toluic acid (COOH=1)
  • 2-METHYL-6-NITROBENZOIC ACID 98+%
CAS:
13506-76-8
MF:
C8H7NO4
MW:
181.15
EINECS:
236-833-3
Product Categories:
  • Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
  • 1
Mol File:
13506-76-8.mol
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2-METHYL-6-NITROBENZOIC ACID Chemical Properties

Melting point:
153-157 °C (lit.)
Boiling point:
314.24°C (rough estimate)
Density 
1.4283 (rough estimate)
refractive index 
1.5468 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMSO, Methanol
form 
Solid
pka
pK1:1.87 (25°C)
color 
Pale Yellow
BRN 
2050804
CAS DataBase Reference
13506-76-8(CAS DataBase Reference)
EPA Substance Registry System
2-Methyl-6-nitrobenzoic acid (13506-76-8)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29163990

MSDS

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2-METHYL-6-NITROBENZOIC ACID Usage And Synthesis

Chemical Properties

light orange to yellow-brown crystalline powder

Uses

2-Methyl-nitrobenzoic acid acts as herbicide due to the anthranilic acid moiety within the substructure.

General Description

Pale yellow needles or tan powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

2-METHYL-6-NITROBENZOIC ACID is a nitrated carboxylic acid. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry.

Fire Hazard

Flash point data for 2-METHYL-6-NITROBENZOIC ACID are not available; however, 2-METHYL-6-NITROBENZOIC ACID is probably combustible.

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