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4-Methyl-3-nitrobenzoic acid methyl ester

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4-Methyl-3-nitrobenzoic acid methyl ester Basic information

Product Name:
4-Methyl-3-nitrobenzoic acid methyl ester
Synonyms:
  • 4-METHYL-3-NITROBENZOIC ACID METHYL ESTER
  • METHYL 3-NITRO-4-METHYLBENZOATE
  • METHYL 4-METHYL-3-NITROBENZOATE
  • 3-NITRO-P-TOLUIC ACID METHYL ESTER
  • RARECHEM AL BF 0233
  • 4-Methyl-3-Nitro Benzoic Acid Methyl Ester Methyl 4-Methyl-3-Nitro Benzoate
  • 3-NITRO-4-METHYLBENZOICACIDMETHYLESTER
  • BENZOICACID,4-METHYL-3-NITRO-,METHYLESTER(9CI)
CAS:
7356-11-8
MF:
C9H9NO4
MW:
195.17
EINECS:
230-886-6
Product Categories:
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Chemical Synthesis
  • Esters
  • Organic Building Blocks
  • Intermediates of Dyes and Pigments
  • Aromatic Esters
  • Organic acids
  • Benzenes
Mol File:
7356-11-8.mol
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4-Methyl-3-nitrobenzoic acid methyl ester Chemical Properties

Melting point:
49-53°C
Boiling point:
298.0±20.0 °C(Predicted)
Density 
1?+-.0.06 g/cm3(Predicted)
Flash point:
110 °C
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in methanol.
form 
powder to crystal
color 
White to Light yellow
CAS DataBase Reference
7356-11-8(CAS DataBase Reference)
EPA Substance Registry System
Benzoic acid, 4-methyl-3-nitro-, methyl ester (7356-11-8)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22-43
Safety Statements 
37/39
WGK Germany 
2
TSCA 
Yes
HS Code 
29163990

MSDS

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4-Methyl-3-nitrobenzoic acid methyl ester Usage And Synthesis

Synthesis

Methyl 4-methyl-3-nitrobenzoate is synthesized by the following steps:Acid 33 (100 g, 0.552 mol) was dissolved in MeOH (1000 ml). Conc.  H2SO4 (30 ml) was added cautiously to this solution. The mixture was  refluxed for 8 hours. Solvent was distilled off. Ice-cold water was added  to the residue. It was then extracted with EtOAc, washed with NaHCO3 solution, water, dried (anhydrous Na2SO4), filtered and concentrated in  vacuo to furnish faint yellow a solid. (91.57 g).

Chemical Properties

White solid

Uses

Methyl 4-methyl-3-nitrobenzoate is used as pharmaceutical intermediate.

4-Methyl-3-nitrobenzoic acid methyl ester Preparation Products And Raw materials

Preparation Products

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