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(S)-1,2,4-Butanetriol

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(S)-1,2,4-Butanetriol Basic information

Product Name:
(S)-1,2,4-Butanetriol
Synonyms:
  • (S)-Butane-1,2,4-triol
  • (S)-1,2,4-Butanetriol,95%,99% ee
  • (2S)-(-)-1,2,4-Trihydroxybutane
  • ASTM D6584 1,2,4-Butanetriol Solution
  • (2S)-BUTANE-1,2,4-TRIOL
  • 1,2,4-BUTANETRIOL, (S)
  • BUTANETRIOL(CAS#: 42890-76-6),INT STD#1&
  • (S)-()-1,2,4-Butanetriol 98%
CAS:
42890-76-6
MF:
C4H10O3
MW:
106.12
EINECS:
610-080-4
Product Categories:
  • Chiral Building Blocks
  • Organic Building Blocks
  • Chiral Building Blocks
  • Simple Alcohols (Chiral)
  • Synthetic Organic Chemistry
  • Polyols
Mol File:
42890-76-6.mol
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(S)-1,2,4-Butanetriol Chemical Properties

Boiling point:
150 °C0.04 mm Hg(lit.)
alpha 
-30 º (c=1, MeOH)
Density 
1.19 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.475(lit.)
Flash point:
>110°C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Sparingly), Water (Slightly)
pka
14.02±0.20(Predicted)
form 
Oil
Specific Gravity
1.190
color 
Colourless
optical activity
[α]19/D 28±2, c = 1 in methanol
Water Solubility 
soluble
Sensitive 
Hygroscopic
BRN 
1719408
Stability:
Hygroscopic
CAS DataBase Reference
42890-76-6(CAS DataBase Reference)
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Safety Information

Hazard Codes 
F,Xn
Risk Statements 
36/37/38-41-20/21/22-11
Safety Statements 
23-24/25-39-26-16-36/37-28-33-29-9
RIDADR 
UN 3316 9/PG 2
WGK Germany 
3
3-10-21
HS Code 
2905490090

MSDS

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(S)-1,2,4-Butanetriol Usage And Synthesis

Description

(S)-(-)-1,2,4-Butanetriol can be prepared via reduction of (S)-malic acid in the presence of borane-dimethyl sulfide. (S)-(-)-1,2,4-Butanetriol may be used as a starting material in the enantioselective total syntheses of (+)-azimine and (+)-carpaine. It can also be used to prepare the organic building blocks (+)-3,4-epoxy-1-butanol, (2S,4S)-4-(hydroxymethyl)-2-ferrocenyl-1,3-dioxan, (S)-1,2,4-triacetoxybutane via acetylation with acetic anhydride, and (S)-1,2,4-tris-(3,5-dinitrobenzoy1oxy)butane via esterification with 3,5-dinitrobenzoyl chloride, and so on.

Chemical Properties

clear colorless viscous liquid

Uses

Glycerophospholipids act as regulators of various enzyme activities, and can be used as biological markers to indicate pathological states.

Definition

ChEBI: 2-deoxyerythritol is a secondary alcohol.

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