Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Chemical Properties

Melting point:

159 °C (dec.)(lit.)

storage temp. 

Inert atmosphere,Room Temperature

solubility 

Soluble in chloroform

form 

crystal

color 

dark red

Water Solubility 

insoluble

Sensitive 

Air Sensitive

Exposure limits

ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26

WGK Germany 

3

Hazard Note 

Irritant

TSCA 

No

HS Code 

28439000

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Usage And Synthesis

Reaction

1. Rhodium catalyzed contrasteric regiocontrolled hydrogenative couplings of nonsymmetric 1,3-diynes to ethyl glyoxalate
2. Rhodium catalyzed reductive Mannich coupling of vinyl ketones to N-Sulfonylimines mediated by hydrogen
3. Rhodium catalyzed asymmetric synthesis of Sitagliptin
4. Rhodium catalyzed asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate(99326-34-8)Related Product Information

• Trifluoromethanesulfonic acid
• 1,5-Cyclooctadiene
• Levofloxacin Methylate
• Rhodium
• Pefloxacin mesylate
• Trifluoromethanesulfonic anhydride
• 1,3-CYCLOOCTADIENE
• Danofloxacin mesylate
• BIS(1,5-CYCLOOCTADIENE)IRIDIUM (I) TETRAFLUOROBORATE
• Chloro(1,5-cyclooctadiene)iridium(I) dimer
• Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
• Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
• BIS(1 5-CYCLOOCTADIENE)RHODIUM(I)
• Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium
• Trifluoromethane
• Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate