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Methyl 1-cyclohexene-1-carboxylate

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Methyl 1-cyclohexene-1-carboxylate Basic information

Product Name:
Methyl 1-cyclohexene-1-carboxylate
Synonyms:
  • Methyl cyclohex-1-ene-1-carboxylate 98%
  • 1-Cyclohexene-1-carboxylic acid, methyl ester
  • METHYL 3,4,5,6-TETRAHYDROBENZOATE
  • METHYL 1-CYCLOHEXENE-1-CARBOXYLATE
  • METHYL 1-CYCLOHEXENECARBOXYLATE
  • METHYL CYCLOHEXENE-1-CARBOXYLATE
  • CYCLOHEXENE-1-CARBOXYLIC ACID METHYL ESTER
  • CYCLOHEX-1-ENECARBOXYLIC ACID METHYL ESTER
CAS:
18448-47-0
MF:
C8H12O2
MW:
140.18
EINECS:
242-331-5
Product Categories:
  • C8 to C9
  • Carbonyl Compounds
  • Esters
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Aromatic Esters
  • heterocyclic/Aliphatic series
  • Chemical Synthesis
  • Organic Building Blocks
Mol File:
18448-47-0.mol
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Methyl 1-cyclohexene-1-carboxylate Chemical Properties

Boiling point:
190-192 °C
Density 
1.028 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.477
Flash point:
165 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Clear colorless
Water Solubility 
insoluble
BRN 
1071971
CAS DataBase Reference
18448-47-0(CAS DataBase Reference)
NIST Chemistry Reference
Methyl 1-cyclohexene-1-carboxylate(18448-47-0)
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Safety Information

Safety Statements 
23-24/25
WGK Germany 
3
10-23
HS Code 
29162090

MSDS

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Methyl 1-cyclohexene-1-carboxylate Usage And Synthesis

Chemical Properties

clear colorless liquid

Uses

Methyl 1-cyclohexene-1-carboxylate is used in the diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols and methyl -7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate.

Synthesis Reference(s)

The Journal of Organic Chemistry, 33, p. 1550, 1968 DOI: 10.1021/jo01268a053
Tetrahedron Letters, 17, p. 453, 1976

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