ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organonickel > 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II) Basic information
- Product Name:
- 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)
- Synonyms:
-
- [5,10,15,20-Tetraphenylporphinato(2-)]nickel
- [meso-Tetraphenylporphinato(2-)]nickel
- 21H,23H-Porphine, 5,10,15,20-tetraphenyl-, nickel complex
- Nickel tetraphenylporphine
- Nickel tetraphenylporphyrin
- Nickel(II) 5,10,15,20-tetraphenylporphine
- Nickel(II) tetraphenylphorphyrin
- Nickel, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-, (SP-4-1)-
- CAS:
- 14172-92-0
- MF:
- C44H28N4Ni
- MW:
- 671.41
- Product Categories:
-
- metal porphine (porphyrin) complex
- Porphyrins
- Synthetic Porphyrins
- Mol File:
- 14172-92-0.mol
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5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II) Chemical Properties
- Melting point:
- >300 °C
- storage temp.
- 2-8°C, protect from light, stored under nitrogen
- form
- crystal
- color
- purple
- Water Solubility
- Insoluble in H2O; soluble in CHCl3; slightly soluble in ether, benzene, hexane, and methanol.
- λmax
- 525 nm (2nd)
- InChIKey
- CXIRWLOIAQYBLZ-DAJBKUBHSA-N
- SMILES
- N12[Ni]N3C4C=CC3=C(C3C=CC(N=3)=C(C3=CC=CC=C3)C1=CC=C2C(C1=CC=CC=C1)=C1C=CC(C=4C2=CC=CC=C2)=N1)C1=CC=CC=C1 |c:7,14,41,t:36|
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Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22
- Safety Statements
- 37/39-26-36
- WGK Germany
- 3
- HS Code
- 29310099
MSDS
- Language:English Provider:ACROS
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5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II) Usage And Synthesis
Chemical Properties
dark purple crystalline powder or crystals
Uses
Nickel(II) Tetraphenylporphyrinate is an electron transfer agent and catalyst for aryl halogen exchange reactions. It could be used in cyclizations of saturated ο-iodo ketones and hydrogenation of alkenes.
reaction suitability
reagent type: catalyst
core: nickel
Purification Methods
Purify it by chromatography on neutral (Grade I) alumina, followed by recrystallisation from CH2Cl2/MeOH [Yamashita J Phys Chem 91 3055 1987]. [Beilstein 26 III/IV 1960.]
Precautions
Stable in air and water. Some nickel compounds are known carcinogens, so standard safety precautions apply.
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)Supplier
Chongqing Xingcan Pharmaceutical Technology Co., Ltd. Gold
- Tel
- 023-13650506873 19923294409
- xingcanyaoye@sina.com
He' nan province outai high-tech co., ltd Gold
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- 0370-15090066789 15090066789
- 409928888@qq.com
J & K SCIENTIFIC LTD.
- Tel
- 18210857532; 18210857532
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006356688 18621169109
- market03@meryer.com
Beijing HwrkChemical Technology Co., Ltd
- Tel
- 18515581800 18501085097
- sales.bj@hwrkchemical.com
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5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)(14172-92-0)Related Product Information
- TPP
- TPPS
- meso-Tetratolylporphyrin-Mn(III)chloride
- meso-Tetrakis(4-chlorophenyl)porphyrin-Mn(III)chloride
- manganese(III) meso-tetraphenylporphine-μ-oxo dimer
- IRON (III) MESO-TETRAPHENYLPORPHINE-MU-OXO DIMER
- CHLORIDE IONOPHORE I
- meso-Tetrakis(4-chlorophenyl)porphyrin-Fe(III)chloride
- COPPER TPP
- 5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III)chloride
- 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
- ZINC MESO-TETRAPHENYLPORPHINE
- PORPHINE
- Protoporphyrin IX
- 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)
- meso-Tetratolylporphyrin-Ni(II)
- SALOR-INT L163279-1EA
- 5,10,15,20-TETRAKIS-(3-METHOXY-4-HYDROXY-PHENYL)-PORPHYRIN-NI-(II)