Basic information Safety Supplier Related

METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE

Basic information Safety Supplier Related

METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE Basic information

Product Name:
METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE
Synonyms:
  • (R)-(+)-3-Bromoisobutyric Acid Methyl Ester (R)-(+)-3-Bromo-2-Methylpropionic Acid Methyl Ester Methyl (R)-(+)-3-Bromo-2-methylpropionate
  • Methyl (R)-(+)-3-bromo-2-methylpropionate 97%
  • (R)-Methyl 3-bromo-2-methylpropanoate
  • Methyl (R)-(+)-3-Bromoisobutyrate
  • (+)-METHYL (R)-3-BROMO-2-METHYLPROPIONATE
  • METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE
  • METHYL (R)-(+)-3-BROMOISOBUTYRATE
  • (+)-METHYL (R)-BETA-BROMOISOBUTYRATE
CAS:
110556-33-7
MF:
C5H9BrO2
MW:
181.03
Product Categories:
  • Carboxylic Acids (Chiral)
  • Chiral Building Blocks
  • Synthetic Organic Chemistry
Mol File:
110556-33-7.mol
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METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE Chemical Properties

Boiling point:
85 °C37 mm Hg(lit.)
Density 
1.422 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.455
Flash point:
165 °F
storage temp. 
Sealed in dry,Room Temperature
form 
liquid
Appearance
Colorless to light yellow Liquid
optical activity
[α]20/D +16°, neat
BRN 
1720833
InChI
InChI=1S/C5H9BrO2/c1-4(3-6)5(7)8-2/h4H,3H2,1-2H3/t4-/m0/s1
InChIKey
FKWNAVCXZSQYTA-BYPYZUCNSA-N
SMILES
C(OC)(=O)[C@@H](C)CBr
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2915907098

MSDS

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METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE Usage And Synthesis

Uses

Methyl (R)-(+)-3-bromo-2-methylpropionate can be used as a reactant to prepare:

  • (S)-3-(6-Methoxy-pyridin-3-yl)-2-methylpropionic acid methylester by reacting with 5-bromo-2-methoxy pyridine via nucleophilic displacement reaction.
  • Decahydroisoquinoline derivative (NVP-ACQ090) as a potent antagonist of somatostatin sst3 receptor.

It can also be used as a reference compound in the enantioselective alkylation reaction of hydrophobic vitamin B12 derivatives.

METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATESupplier

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