LITHIUM DIETHYLAMIDE
LITHIUM DIETHYLAMIDE Basic information
- Product Name:
- LITHIUM DIETHYLAMIDE
- Synonyms:
-
- LITHIUM DIETHYLAMIDE
- Ethanamine, N-ethyl-, lithium salt
- Lithiumdiethylamideoffwhitepowder
- LITHIUM DIETHYLAMIDE, 95+%
- (Diethylamino)lithium
- Diethylaminolithium
- Diethyllithioamine
- N-Lithiodiethylamine
- CAS:
- 816-43-3
- MF:
- C4H12LiN
- MW:
- 81.09
- EINECS:
- 212-433-4
- Product Categories:
-
- Chemical Synthesis
- Organic Bases
- Synthetic Reagents
- metal amide
- Mol File:
- 816-43-3.mol
More
Less
LITHIUM DIETHYLAMIDE Chemical Properties
- solubility
- sol THF, Et2O, Et2O-hexane mixtures, Et2O-benzene mixtures; insol hydrocarbon solvents
- pka
- pKa = 31.7
- form
- solid
- color
- off-white to light-orange
- Sensitive
- moisture sensitive
More
Less
Safety Information
- Hazard Codes
- F,C
- Risk Statements
- 17-34
- Safety Statements
- 16-26-27-36/37/39-45
- RIDADR
- UN 3393 4.2/PG 1
- WGK Germany
- 3
- HazardClass
- 4.2
- PackingGroup
- I
MSDS
- Language:English Provider:SigmaAldrich
More
Less
LITHIUM DIETHYLAMIDE Usage And Synthesis
Uses
Lithium Diethylamide is used as a strong base; nitrogen nucleophile.
Synthesis Reference(s)
1.Normant, H.; Cuvigny, T.; Reisdorf, D. CR(C) 1969, 268, 521.
2. Gaudemar-Bardone, F.; Gaudemar, M. S 1979, 463.
Synthesis
Lithium Diethylamide is synthesized by treating diethylamine with Phenyllithium or n-Butyllithium or, alternatively, by treating diethylamine with Lithium metal in the presence of Hexamethylphosphoric Triamide or an electron acceptor.1,2
LITHIUM DIETHYLAMIDESupplier
Shanghai Boyle Chemical Co., Ltd.
- Tel
- 021-50182298 021-50180596
- sales@boylechem.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
Antai Fine Chemical Technology Co.,Limited
- Tel
- 18503026267
- info@antaichem.com
Shaanxi Dideu Medichem Co. Ltd
- Tel
- 029-81024372 15029046529
- 1027@dideu.com