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2,2-Dimethyl-4-pentenal

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2,2-Dimethyl-4-pentenal Basic information

Product Name:
2,2-Dimethyl-4-pentenal
Synonyms:
  • 2,2-DIMETHYL-4-PENTENAL
  • 2,2-Dimethyl-4-penteneal
  • 2,2-DIMETHYL-4-PENTENAL, TECH., 90%
  • 2,2-Dimethyl-4-pentenal, stabilized, 97%
  • 2,2-dimethylpent-4-enal
  • 2,2-DiMethyl-4-pentenal, stabilized, 97% 5ML
  • 2,2-Dimethyl-4-pentenal technical grade, 90%, contains 1000 ppm hydroquinone as stabilizer
  • 2,2-Dimethyl-4-pentenal,97%,stabilized
CAS:
5497-67-6
MF:
C7H12O
MW:
112.17
EINECS:
226-834-7
Product Categories:
  • Aldehydes
  • C7
  • Carbonyl Compounds
Mol File:
5497-67-6.mol
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2,2-Dimethyl-4-pentenal Chemical Properties

Melting point:
-53.35°C (estimate)
Boiling point:
124-125 °C (lit.)
Density 
0.825 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.4203(lit.)
Flash point:
65 °F
storage temp. 
2-8°C
form 
Liquid
color 
Clear colorless to light yellow
NIST Chemistry Reference
4-Pentenal, 2,2-dimethyl-(5497-67-6)
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Safety Information

Hazard Codes 
F,Xi,Xn
Risk Statements 
11-36/37/38-22
Safety Statements 
16-26-33-36
RIDADR 
UN 1989 3/PG 3
WGK Germany 
-
HazardClass 
3.1
PackingGroup 
II
HS Code 
29121990

MSDS

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2,2-Dimethyl-4-pentenal Usage And Synthesis

Chemical Properties

clear colorless to light yellow liquid

Uses

2,2-Dimethyl-4-pentenal has been used:

  • as electrophile in the synthesis of rearranged bicyclo[6.3.0]undecane isoprenoid skeleton of cyclooctenoid sesquiterpene dactylol and 3a-epi-dactylol
  • in the preparation of imine ligand via condensation with primary amine

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 7, p. 177, 1990
Synthetic Communications, 10, p. 273, 1980 DOI: 10.1080/00397918008062750
Tetrahedron Letters, 14, p. 3, 1973

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