Allyltrimethoxysilane Chemical Properties

Boiling point:

146-148 °C (lit.)

Density 

0.963 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.405(lit.)

Flash point:

88 °F

storage temp. 

Inert atmosphere,2-8°C

form 

Liquid

color 

Clear colorless

Specific Gravity

0.96

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

BRN 

2350745

InChIKey

LFRDHGNFBLIJIY-UHFFFAOYSA-N

EPA Substance Registry System

Silane, trimethoxy-2-propenyl- (2551-83-9)

Safety Information

Hazard Codes 

Xi

Risk Statements 

10-36/37/38

Safety Statements 

26-36-37/39-16

RIDADR 

UN 1993 3/PG 3

WGK Germany 

3

F 

10-21

TSCA 

Yes

HazardClass 

3.1

PackingGroup 

II

HS Code 

29319090

MSDS

• Language:English Provider:SigmaAldrich

Allyltrimethoxysilane Usage And Synthesis

Chemical Properties

Colorless to Almost colorless clear liquid to slightly cloudy liquid

Uses

Allyltrimethoxysilane is an allylating reagent that can be used for the allylation of carbonyl compounds such as aldehydes, ketones, and imines. Homoallylic alcohols and amines are obtained via the C-C bond forming reaction. It can also be used to synthesize homoallylic α-branched amines from aromatic and aliphatic aldehyde hydrazones, and ketone hydrazones.

Application

Allyltrimethoxysilane as the Reagent of Double Bond Introduction to Porous Silica for Preparation of a Chiral Stationary Phase in Comparison with Allyltriethoxysilane.
Allylation of ketones, aldehydes and imines with dual activation of a Lewis Acid and fluoride ion.
Used in the regioselective generation of the thermodynamically more stable enol trimethoxysilyl ethers, which in turn are used in the asymmetric generation of quaternary carbon centers.
Converts arylselenyl bromides to arylallylselenides.
Allylates aryl iodides.
Allyltrimethoxysilane serves as a remarkable reagent in Silver-Catalyzed Asymmetric Allylation.

Allyltrimethoxysilane(2551-83-9)Related Product Information

• ALLYLTRIETHOXYSILANE
• ALLYLTRIISOPROPYLSILANE
• Chloro(chloromethyl)dimethylsilane
• Palladium chloride
• Allyltrimethylsilane
• Acetylene
• Allyltriethylsilane
• Allylboronic acid pinacol ester
• ALLYL ISOPROPYL ACETYLUREA
• Allyl Benzyl Ether
• Sodium allylsulfonate
• Allylmagnesium chloride
• Allyl methyl sulfide
• Allylthiourea
• Methyl allyl disulfide
• ALLYLOXY-T-BUTYLDIMETHYLSILANE
• allyltrimethylammonium chloride
• Allyltributyltin