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Orcinol monohydrate

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Orcinol monohydrate Basic information

Product Name:
Orcinol monohydrate
Synonyms:
  • ORCINOL extrapure
  • 3,5-Dihydroxytoluene, 5-Methylresorcinol
  • 5-Methylresorcinol 
  • Orcinol Monohydrate, 99% 25GR
  • Orcinol monohydrate,99%
  • 1,3-Benzenediol,5-Methyl-,hydrate(1:1)
  • 5-Methylbenzene-1,3-diol hydrate
  • Moss Black Dove
CAS:
6153-39-5
MF:
C7H10O3
MW:
142.15
EINECS:
678-599-9
Product Categories:
  • Aromatic Hydrocarbons (substituted) & Derivatives
Mol File:
6153-39-5.mol
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Orcinol monohydrate Chemical Properties

Melting point:
56-61 °C
Boiling point:
290 °C
Density 
1.29
Flash point:
147°C/5mm
storage temp. 
room temp
solubility 
H2O: soluble50mg/mL
form 
Powder, Crystals or Flakes
color 
off-white to tan
Water Solubility 
SOLUBLE
Sensitive 
Air Sensitive
Merck 
14,6864
BRN 
5103474
Stability:
Stable. Incompatible with strong oxidizing agents, strong acids. May be air-sensitive.
CAS DataBase Reference
6153-39-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
36/37/38-22-20/21/22
Safety Statements 
37/39-26-36
WGK Germany 
3
RTECS 
VH2100000
TSCA 
Yes
HS Code 
29072100

MSDS

  • Language:English Provider:ACROS
  • Language:English Provider:ALFA
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Orcinol monohydrate Usage And Synthesis

Description

A pyranoquinolone alkaloid found in Oricia suaveolens, this base does not form salts with mineral acids. The structure has been established by synthesis as 6:7- dimethoxy-N-methylflindersine.

Chemical Properties

White to beige crystalline powder

Uses

Reagent for sugars.

Uses

5-Methylbenzene-1,3-diol Hydrate is the hydrated form of 3,5-Dihydroxytoluene(D454760); 3,5-Dihydroxytoluene is found in lichen fungi and can improve functional properties of lysozyme.

Uses

Orcinol monohydrate is usually used to prepare colorimetric reagents for the determination of RNA, DNA,and hexoses.

General Description

Orcinol is a small-molecule natural phenol involved in the production of a dye called orcein used for the staining of cells and chromosomes. Orcinol monohydrate is usually used to prepare a colorimetric reagent known as Bial′s reagent for the determination of RNA, DNA, and hexoses.

Purification Methods

Purify orcine by recrystallisation from H2O as the monohydrate. It sublimes in vacuo, and the anhydrous compound has m 106.5-108o (110o, 108o). It can be recrystallised from CHCl3 (plates) or *C6H6 (needles or prisms). [UV: Kiss et al. Bull Soc Chim Fr 275 1949, Adams et al. J Am Chem Soc 62 732 1940.]

References

Abe, Taylor., Phytochern., 10, 1167 (1971)

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