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Diphenylmethoxyphosphine

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Diphenylmethoxyphosphine Basic information

Product Name:
Diphenylmethoxyphosphine
Synonyms:
  • Diphenylphosphinooxymethane
  • Methoxydiphenylphosphane
  • Methyl diphenylphosphinite 97%
  • Diphenylphosphinous Acid Methyl Ester Methyl Diphenylphosphinite
  • NSC 171167
  • DIPHENYLPHOSPHINOUS ACID METHYL ESTER
  • DIPHENYLMETHOXYPHOSPHINE
  • AURORA KA-1329
CAS:
4020-99-9
MF:
C13H13OP
MW:
216.22
EINECS:
223-683-9
Product Categories:
  • Ligand
  • Phosphine Ligands
  • Synthetic Organic Chemistry
Mol File:
4020-99-9.mol
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Diphenylmethoxyphosphine Chemical Properties

Boiling point:
149 °C6 mm Hg(lit.)
Density 
1.078 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.604(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
form 
Liquid
Specific Gravity
1.078
color 
Clear colorless to very slightly yellow
Sensitive 
Air & Moisture Sensitive
BRN 
1640480
CAS DataBase Reference
4020-99-9(CAS DataBase Reference)
NIST Chemistry Reference
Methyl diphenylphosphinite(4020-99-9)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-37/39-36
RIDADR 
UN 2810 6.1/PG 3
WGK Germany 
3
HazardClass 
6.1
PackingGroup 
III
HS Code 
29310099

MSDS

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Diphenylmethoxyphosphine Usage And Synthesis

Chemical Properties

Colorless to light yellow liqui

Uses

Ased as:

  • Catalyst for hydroformylative desymmetrization of bisalkenyl carbinols and bishomoallylic carbinols
  • Ligand in rhodium-catalyzed hydroformylation of bishomoallylic alcohols
  • Calatyst in preparation of γ-lactones via branched-regioselective hydroformylation reactions
  • Ligand for nickel-catalyzed hydrocyanation reactions
  • Catalyst in annulation reactions

DiphenylmethoxyphosphineSupplier

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