Basic information Safety Supplier Related
ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Esters >  Carboxylic Acid Esters >  tert-Butyl phenyl carbonate

tert-Butyl phenyl carbonate

Basic information Safety Supplier Related

tert-Butyl phenyl carbonate Basic information

Product Name:
tert-Butyl phenyl carbonate
Synonyms:
  • (2-tert-butylphenyl) carbonate
  • (tert-Butoxycarbonyloxy)benzene
  • Carbonic acid O-phenyl O-tert-butyl ester
  • Carbonic acid O-tert-butyl O-phenyl ester
  • Carbonic acid tert-butylphenyl ester
  • Einecs 229-601-8
  • Carbonicacidtert-butylesterphenylester
  • ert-Butyl phenyl carbonate
CAS:
6627-89-0
MF:
C11H14O3
MW:
194.23
EINECS:
229-601-8
Product Categories:
  • Organic Building Blocks
  • Carbonates
  • Carbonyl Compounds
Mol File:
6627-89-0.mol
More
Less

tert-Butyl phenyl carbonate Chemical Properties

Boiling point:
83 °C/0.6 mmHg (lit.)
Density 
1.05 g/mL at 20 °C (lit.)
refractive index 
n20/D 1.480
Flash point:
214 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly)
form 
Liquid or Low Melting Solid
color 
Colorless
Water Solubility 
Slightly soluble in water.
BRN 
2361602
NIST Chemistry Reference
Carbonic acid 1,1-dimethylethyl ester(6627-89-0)
More
Less

Safety Information

Safety Statements 
23-24/25
WGK Germany 
3
21
HS Code 
29209090

MSDS

More
Less

tert-Butyl phenyl carbonate Usage And Synthesis

Chemical Properties

Clear light yellow liquid

Uses

tert-Butyl phenyl carbonate is used in determination of octanol-water partition coefficients by microemulsion electrokinetic chromatography. It is also used in the synthesis of 2-nitroindoles and as a reagent for mono-Boc protection of α,ω-diamines.

Purification Methods

If IR is free from OH, then purify it by redistillation; otherwise dissolve it in Et2O, wash it with 5% HCl, then H2O, dry it (MgSO4), evaporate and distil it through a Claisen head under vacuum. Care should be taken as distillation of large quantities can lead to decomposition with liberation of CO2 and isobutylene; use the necessary precautions. [Carpino J Am Chem Soc 79 98 1957, Beilstein 6 IV 629.]

tert-Butyl phenyl carbonateSupplier

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Email
market03@meryer.com
Chembest Research Laboratories Limited
Tel
021-20908456
Email
sales@BioChemBest.com
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Email
Sales-CN@TCIchemicals.com
Energy Chemical
Tel
021-021-58432009 400-005-6266
Email
sales8178@energy-chemical.com