Phenylhydrazine hydrochloride
- Product Name
- Phenylhydrazine hydrochloride
- CAS No.
- 59-88-1
- Chemical Name
- Phenylhydrazine hydrochloride
- Synonyms
- hydrazinium ChL;PHENYLHYDRAZINE HCL;Phenylhydrazine hydr;PHENYLHYDRAZINIUM CHLORIDE;phenylhydrazinhydrochlorid;PhenylhydraziniumchlorideGR;Phenylhydrazine hydrochlorid;phenyl-hydrazinhydrochloride;PHENYLHYDRAZINE CHLORHYDRATE;PhenylhydraziniumChloride>
- CBNumber
- CB0101763
- Molecular Formula
- C6H9ClN2
- Formula Weight
- 144.6
- MOL File
- 59-88-1.mol
Phenylhydrazine hydrochloride Property
- Melting point:
- 250-254 °C (dec.)(lit.)
- Boiling point:
- 236.22°C (rough estimate)
- Density
- 1.1672 (rough estimate)
- refractive index
- 1.5210 (estimate)
- storage temp.
- Store below +30°C.
- solubility
- H2O: soluble50mg/mL
- form
- Fine Crystalline Powder
- color
- White to light yellow or pinkish-beige
- PH
- 2.6-2.9 (50g/l, H2O)
- Water Solubility
- 50 g/L (20 ºC)
- Merck
- 14,7293
- BRN
- 3594958
- Stability:
- Stable. Incompatible with most common metals.
- InChIKey
- JOVOSQBPPZZESK-UHFFFAOYSA-N
- CAS DataBase Reference
- 59-88-1(CAS DataBase Reference)
- EPA Substance Registry System
- Phenylhydrazine hydrochloride (59-88-1)
Safety
- Hazard Codes
- T,N
- Risk Statements
- 45-23/24/25-36/38-43-48/23/24/25-50-68
- Safety Statements
- 53-45-61
- RIDADR
- UN 2811 6.1/PG 3
- WGK Germany
- 3
- RTECS
- MV9000000
- F
- 3-8-10-23
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29280090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H341Suspected of causing genetic defects
H350May cause cancer
H372Causes damage to organs through prolonged or repeated exposure
H400Very toxic to aquatic life
- Precautionary statements
-
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 114715
- Product name
- Phenylhydrazine hydrochloride
- Purity
- ≥99%
- Packaging
- 5g
- Price
- $24.5
- Updated
- 2024/03/01
- Product number
- 114715
- Product name
- Phenylhydrazine hydrochloride
- Purity
- ≥99%
- Packaging
- 100g
- Price
- $129
- Updated
- 2024/03/01
- Product number
- 1.07253
- Product name
- Phenylhydrazinium chloride
- Purity
- for analysis
- Packaging
- 100g
- Price
- $282
- Updated
- 2024/03/01
- Product number
- 1.07253
- Product name
- Phenylhydrazinium chloride
- Purity
- for analysis
- Packaging
- 250g
- Price
- $644
- Updated
- 2024/03/01
- Product number
- P0184
- Product name
- Phenylhydrazine Hydrochloride
- Purity
- >98.5%(T)
- Packaging
- 25g
- Price
- $26
- Updated
- 2024/03/01
Phenylhydrazine hydrochloride Chemical Properties,Usage,Production
Chemical Properties
Phenylhydrazine is a colorless to pale yellow liquid or solid with a weak aromatic odor.
Uses
manufacture of dyes, antipyrine, nitron (a stabilizer for explosives); reagent for sugars, aldehydes, ketones.
Uses
Phenylhydrazine hydrochloride is used as a selective mannosidase inhibitor. It is used in the study of tyrosine phosphorylation of janus protein tyrosine kinase in the EPO-responsive normal erythroblastoid cells of anemic mice. It is used in steroid assays and as an N-protecting reagent. Its free base, phenylhydrazine is used to prepare indoles, which find application as intermediates in the synthesis of various dyes and pharmaceuticals.
Definition
ChEBI: Phenylhydrazine hydrochloride is a hydrochloride resulting from the reaction of equimolar amounts of phenylhydrazine and hydrogen chloride. It contains a phenylhydrazine.
General Description
White to tan solid with a weak aromatic odor.
Air & Water Reactions
Forms corrosive acidic solutions.
Reactivity Profile
Phenylhydrazine hydrochloride may be corrosive to metals [USCG, 1999].
Health Hazard
Phenylhydrazine hydrochloride is poisonous if swallowed or if fumes are inhaled. Dust is irritating to eyes, nose, and throat. Phenylhydrazine is a chronic poison. Phenylhydrazine is an industrial substance suspect of carcinogenic potential for humans.
Fire Hazard
Toxic and irritating hydrogen chloride and oxides of nitrogen may be produced in fire. May be corrosive to metals. Hazardous polymerization may not occur.
Biochem/physiol Actions
Phenylhydrazine hydrochloride causes acute hemolysis when injected intraperitoneally in to wild-type and Hp and Hx single-null mice. It suppresses the horseradish peroxide (HRP) residual activity in tissue sections of animals.
Safety Profile
Poison by ingestion, intraperitoneal, and subcutaneous routes. Experimental reproductive effects. Questionable carcinogen with experimental neoplastigenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and HCl.
Potential Exposure
Phenylhydrazine is a widely used reagent in conjunction with sugars, aldehydes, and ketones. In addition, to its use in the synthesis of dyes; pharmaceuticals, such as antipyrin; cryogenin, and pyramidone; and other organic chemicals. The hydrochloride salt is used in the treatment of polycythemia vera.
Shipping
UN2572 Phenylhydrazine, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
Purification Methods
Dissolve 100g of phenylhydrazine hydrochloride in 200mL of warm H2O (60-70o) during 1-3hours, then add 1L of boiling EtOH. The solution is filtered, while still hot, through Whatman No 2 filter paper and cooled in a refrigerator. The precipitate is collected on a medium sintered-glass filter and recrystallised twice this way, then washed with cold EtOH, dried thoroughly and stored in a stoppered brown bottle. [Peterson et al. Anal Chem 29 144 1957.] Hough, Powell and Woods [J Chem Soc 4799 1956] boiled the hydrochloride with three times its weight of water, filtered hot (charcoal), added one-third volume of concentrated HCl and cooled to 0o. The crystals were washed with acetone, and dried over P2O5 under vacuum. The salt has also been crystallised from 95% EtOH, and it can be sublimed. [Coleman Org Synth Coll Vol I 442 1941, Beilstein 15 III 71.]
Incompatibilities
Phenylhydrazine is very reactive with carbonyl compounds, strong oxidizers; strong bases; alkali metals; ammonia, lead dioxide (violent). Attacks copper salts, nickel, and chromates.
Waste Disposal
Controlled incineration whereby oxides of nitrogen are removed from the effluent gas by scrubber, catalytic or thermal device.
Phenylhydrazine hydrochloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Phenylhydrazine hydrochloride manufacturers
- Product
- Phenylhydrazine hydrochloride 59-88-1
- Price
- US $30.00-10.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 20 tons
- Release date
- 2023-10-09
- Product
- Phenylhydrazine hydrochloride 59-88-1
- Price
- US $108.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 1000000 tons
- Release date
- 2023-10-30
- Product
- Phenylhydrazine hydrochloride 59-88-1
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2022-12-27