Synthesis
ChemicalBook > CAS DataBase List > 1-Naphthylamine-7-sulfonic acid

1-Naphthylamine-7-sulfonic acid

Synthesis
Product Name
1-Naphthylamine-7-sulfonic acid
CAS No.
119-28-8
Chemical Name
1-Naphthylamine-7-sulfonic acid
Synonyms
SODIUM NAPHTHIONATE;SODIUM NAPTHIONATE;C.I. 26135;CLEVE'S ACID;1.7 Clevs Acid;Cleve's O-acid;1,7-CLEVES ACID;CLEVES ACID-1,7;1,7-CLEVE'S ACID;1,7-cleve's acid
CBNumber
CB0141189
Molecular Formula
C10H9NO3S
Formula Weight
223.25
MOL File
119-28-8.mol
More
Less

1-Naphthylamine-7-sulfonic acid Property

Melting point:
≥300 °C(lit.)
Boiling point:
220°C (rough estimate)
Density 
1.3588 (rough estimate)
refractive index 
1.6500 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Aqueous Base (Slightly), DMSO (Slightly, Sonicated)
form 
Powder
pka
pK1: 3.66 (25°C)
Merck 
14,2351
BRN 
2115629
InChIKey
QEZZCWMQXHXAFG-UHFFFAOYSA-N
CAS DataBase Reference
119-28-8(CAS DataBase Reference)
NIST Chemistry Reference
1-Naphthylamine-7-sulfonic acid(119-28-8)
EPA Substance Registry System
2-Naphthalenesulfonic acid, 8-amino- (119-28-8)
More
Less

Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2585 8/PG 3
WGK Germany 
2
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29214500
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
A7782
Product name
8-Amino-2-naphthalenesulfonic acid
Purity
≥97%
Packaging
25g
Price
$75.5
Updated
2024/03/01
Sigma-Aldrich
Product number
A7782
Product name
8-Amino-2-naphthalenesulfonic acid
Purity
≥97%
Packaging
100g
Price
$201
Updated
2024/03/01
TCI Chemical
Product number
A0356
Product name
8-Amino-2-naphthalenesulfonic Acid
Purity
>97.0%(HPLC)(T)
Packaging
25g
Price
$60
Updated
2024/03/01
TCI Chemical
Product number
A0356
Product name
8-Amino-2-naphthalenesulfonic Acid
Purity
>97.0%(HPLC)(T)
Packaging
500g
Price
$460
Updated
2021/12/16
Alfa Aesar
Product number
J65304
Product name
8-Aminonaphthalene-2-sulfonic acid, 95%
Packaging
25g
Price
$67
Updated
2024/03/01
More
Less

1-Naphthylamine-7-sulfonic acid Chemical Properties,Usage,Production

Synthesis

1-Naphthylamine-7-sulfonic acid can be obtained by sulfonation, nitration, neutralization, reduction and acid precipitation of naphthalene.

Chemical Properties

Brown crystalline. 1-Aminonaphthalene-7-sulfonic acid [119- 28-8]. (8-aminonaphthalene-2-sulfonic acid), 1,7-Cleve’s acid, C10H9NO3S, Mr 223.24, is 0.5 % soluble in water at 25℃ and 3 % soluble at 100 ℃. The sodium, potassium, calcium, and magnesium salts are readily soluble in water but the barium salt is only sparingly soluble. Sulfonation with oleum at 50℃ gives 1- aminonaphthalene-4,7-disulfonic acid. Alkali fusion gives 8-amino-2-naphthol, and Bucherer-type hydrolysis gives 1-hydroxynaphthalene-7-sulfonic acid.

Uses

Intermediate of dyestuff

Uses

8-Amino-2-naphthalenesulfonic acid can be used as a reactant to synthesize:

  • Fe3O4/sulfonated polyaniline composite material via chemical oxidative polymerization with aniline in the presence of magnetite (Fe3O4) nanoparticles.
  • Prismatic crystals of strychnine-8-ammonio-2-naphthalenesulfonate-water by heating with strychnine in water/ethanol solvent mixture.
  • 5-amino-9-dialkylamino benzo[a]phenoxazine dyes (Nile blue analogs) by condensation with N-alkyl or N-sulfo-propyl 4-arylazo-substituted 3-hydroxyaniline.

Application

1-Naphthylamine-7-sulfonic acid can be used as a dye intermediate to prepare dyes such as direct light fast blue B2RL, direct light fast red brown RTL, and sulfur blue CV.

More
Less

1-Naphthylamine-7-sulfonic acid Suppliers

ABCR GmbH & CO. KG
Tel
--
Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
PARAGOS
Tel
--
Fax
--
Email
info@paragos.com
Country
Germany
ProdList
6371
Advantage
39
More
Less

View Lastest Price from 1-Naphthylamine-7-sulfonic acid manufacturers

hebei hongtan Biotechnology Co., Ltd
Product
1-Naphthylamine-7-sulfonic acid 119-28-8
Price
US $30.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
2000kg
Release date
2024-03-25
Hebei Yanxi Chemical Co., Ltd.
Product
1-Naphthylamine-7-sulfonic acid 119-28-8
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-27
Hebei Weibang Biotechnology Co., Ltd
Product
1-Naphthylamine-7-sulfonic acid 119-28-8
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24

119-28-8, 1-Naphthylamine-7-sulfonic acidRelated Search:


  • TIMTEC-BB SBB000621
  • SODIUM NAPTHIONATE
  • SODIUM NAPHTHIONATE
  • SODIUM 1-NAPHTHYLAMINE-4-SULFONATE
  • PARA-NAPHTHIONIC ACID, NA SALT
  • NAPHTHIONIC ACID SODIUM SALT 0.5-WATER
  • NAPHTHIONIC ACID SODIUM SALT
  • NAPHTHYLAMINE-4-SULFONIC ACID SODIUM SALT
  • 1-Amino-7-sulfonaphthalene
  • 1-Aminonaphthalene-7-sulfonic acid
  • 2-Naphthalenesulfonic acid, 8-amino-
  • 2-Naphthalenesulfonicacid,8-amino-
  • 1-Naphthylamine-7-sulfonic acid, Cleves acid-1,7
  • 1.7 Clevs Acid
  • 8-AMino-2-naphthalenesulfonic acid >=97%
  • 8-Amino-2-naphthalenesulfonic acid, 97.5%
  • 1-phthylamine-7-sulfonic acid
  • 8-amino-2-naphthalenesulfonicaci
  • 8-Naphthylamine-2-sulfonic acid
  • beta-Naphthylamine-7-sulfonic acid
  • C.I. 26135
  • Cleve's omega-acid or J-acid
  • Cleve's theta-acid
  • 1,7-CLEVES ACID
  • 1,7-CLEVE'S ACID
  • 1,4-SODIUM NAPHTHIONATE
  • 1-AMINO-4-SULFONAPHTHALENE SODIUM SALT
  • 1-Amino-7-naphthalenesulfonic acid
  • 4-AMINONAPHTHALENE-1-SULFONIC ACID SODIUM SALT
  • 4-AMINONAPHTHALENE-1-SULPHONIC ACID SODIUM SALT
  • 4-AMINO-1-NAPHTHALENESULFONIC ACID SODIUM SALT 0.5-WATER
  • ALPHA-NAPHTHYLAMINE-7-SULFONIC ACID
  • 8-AMINO-2-NAPHTHALENESULFONIC ACID
  • 8-AMINONAPHTHALENE-2-SULFONIC ACID
  • CLEVE'S ACID
  • CLEVES ACID-1,7
  • 1-NAPHTHYLAMINE-4-SULFONIC ACID SODIUM SALT 0.5-WATER
  • 1-NAPHTHYLAMINE-7-SULFONIC ACID
  • 8-Amino-2-naphtalenesulfonic acid
  • 8-aminonaphthalene-2-sulphonic acid
  • 1-NAPHTHYLAMINE-7-SULFONIC ACID TECHN. 97%
  • Cleve's O-acid
  • 8-Amino-naphthalin-2-sulfonsure
  • 8-Amino-2-naphthalenesulfonicAcid&gt
  • 8-Amino-2-naphthaL
  • 1-Naphthylamine-7-sulfonicaci
  • 1-Naphthylamine-7-sulfonic acid ISO 9001:2015 REACH
  • 1-Naphthylamine-7-sulfonic acid 119-28-8
  • (1-NAPHYLAMINE-7-SULFONIC ACID) 1:7 CLEVES ACID
  • 1,7-cleve's acid
  • 119-28-8
  • C10H9O3NS
  • Building Blocks
  • Organic Building Blocks
  • Sulfur Compounds
  • Sulfonic/Sulfinic Acid Salts
  • Sulfonic/Sulfinic Acids
  • Intermediates of Dyes and Pigments