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ChemicalBook > CAS DataBase List > METHYL 3-CYANO-4-METHOXYBENZOATE

METHYL 3-CYANO-4-METHOXYBENZOATE

Uses
Product Name
METHYL 3-CYANO-4-METHOXYBENZOATE
CAS No.
25978-74-9
Chemical Name
METHYL 3-CYANO-4-METHOXYBENZOATE
Synonyms
METHYL 3-CYANO-4-METHOXYBENZOATE;3-Cyano-4-methoxybenzoic acid methyl ester;methyl 3-cyano-4-methoxybenzoate - [M85982];Benzoic acid, 3-cyano-4-methoxy-, methyl ester
CBNumber
CB0144973
Molecular Formula
C10H9NO3
Formula Weight
191.18
MOL File
25978-74-9.mol
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METHYL 3-CYANO-4-METHOXYBENZOATE Property

Melting point:
124 °C
Boiling point:
339.7±27.0 °C(Predicted)
Density 
1.20±0.1 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Appearance
White to yellow Solid
BRN 
2374769
InChI
InChI=1S/C10H9NO3/c1-13-9-4-3-7(10(12)14-2)5-8(9)6-11/h3-5H,1-2H3
InChIKey
RYJSFYBJYKFNCF-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=C(OC)C(C#N)=C1
CAS DataBase Reference
25978-74-9
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Safety

Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37/39
RIDADR 
3439
HazardClass 
6.1
PackingGroup 
III
HS Code 
2926907090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H331Toxic if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
M338278
Product name
Methyl3-Cyano-4-methoxybenzoate
Packaging
100mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC55139
Product name
3-Cyano-4-methoxybenzoic acid methyl ester
Packaging
5G
Price
$60
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC55139
Product name
3-Cyano-4-methoxybenzoic acid methyl ester
Packaging
10g
Price
$90
Updated
2021/12/16
SynQuest Laboratories
Product number
4637-1-U8
Product name
Methyl 3-cyano-4-methoxybenzoate
Packaging
1g
Price
$96
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC55139
Product name
3-Cyano-4-methoxybenzoic acid methyl ester
Packaging
25g
Price
$175
Updated
2021/12/16
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METHYL 3-CYANO-4-METHOXYBENZOATE Chemical Properties,Usage,Production

Uses

Methyl 3-Cyano-4-methoxybenzoate is a useful research chemical.

Synthesis

35450-37-4

25978-74-9

General procedure for the synthesis of methyl 3-cyano-4-methoxybenzoate from methyl 3-bromo-4-methoxybenzoate: to a solution of methyl 3-bromo-4-methoxybenzoate (1.1 g, 4.4 mmol) in dimethylformamide (10 mL) was added cuprous cyanide (1.2 g, 13.2 mmol). The reaction mixture was heated to 140 °C and maintained for 6 hours. After the reaction was completed, it was cooled to room temperature and diluted by adding ethyl acetate (25 mL). The organic phase was washed with saturated sodium chloride solution, dried over anhydrous sodium sulfate and concentrated under reduced pressure. The crude product was purified by fast column chromatography (eluent: petroleum ether/ethyl acetate=10:1) to afford methyl 3-cyano-4-methoxybenzoate (662 mg, 79% yield) as a white solid.

References

[1] Patent: CN106146504, 2016, A. Location in patent: Paragraph 0219; 0220; 0221; 0224; 0225

METHYL 3-CYANO-4-METHOXYBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 3-CYANO-4-METHOXYBENZOATE Suppliers

Aladdin Scientific
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tp@aladdinsci.com
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United States
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Aceschem Inc.
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+1-817863-6948 +1-(817)863-6948
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sales@aceschem.com
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SynQuest Laboratories, Inc.
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Matrix Scientific
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Ryan Scientific, Inc.
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Alfa Aesar
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Pfaltz & Bauer, Inc.
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View Lastest Price from METHYL 3-CYANO-4-METHOXYBENZOATE manufacturers

Capot Chemical Co.,Ltd.
Product
Methyl 3-cyano-4-methoxybenzoate 25978-74-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
kgs
Release date
2023-01-03
Career Henan Chemical Co
Product
METHYL 3-CYANO-4-METHOXYBENZOATE 25978-74-9
Price
US $3.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-10

25978-74-9, METHYL 3-CYANO-4-METHOXYBENZOATERelated Search:


  • METHYL 3-CYANO-4-METHOXYBENZOATE
  • 3-Cyano-4-methoxybenzoic acid methyl ester
  • Benzoic acid, 3-cyano-4-methoxy-, methyl ester
  • methyl 3-cyano-4-methoxybenzoate - [M85982]
  • 25978-74-9
  • 25987-74-9
  • Aromatic Esters