2-(Diphenylphosphino)-biphenyl

Product Name: 2-(Diphenylphosphino)-biphenyl
CAS No.: 13885-09-1
Chemical Name: 2-(Diphenylphosphino)-biphenyl
Synonyms: 2-Diphenylphosphine benzene;2-(DiphenylphosphiNA)-biphenyl;2-(Diphenylphosphino)-biphenyl;biphenyl-2-yldiphenylphosphine;o-Phenylphenyldiphenylphosphane;2-Biphenylyl(diphenyl)phosphine;2-(Diphenylphosphino)biphenyl >2-(Diphenylphosphino)-biphenyl,98%;2-(Diphenylphosphino)-1,1'-biphenyl;1,1'-biphenyl]-2-yldiphenylphosphine
CBNumber: CB01856079
Molecular Formula: C24H19P
Formula Weight: 338.38
MOL File: 13885-09-1.mol

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2-(Diphenylphosphino)-biphenyl Property

Melting point:: 80.0 to 86.0 °C
Boiling point:: 473.2±24.0 °C(Predicted)
storage temp.: Inert atmosphere,Room Temperature
form: Solid
color: White to Almost white
Water Solubility: Slightly soluble in water.
CAS DataBase Reference: 13885-09-1

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Safety

HS Code: 2931.90.9051

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: D4688
Product name: 2-(Diphenylphosphino)biphenyl
Purity: >98.0%(GC)
Packaging: 1g
Price: $35
Updated: 2025/07/31

TRC

Product number: D492738
Product name: 2-(Diphenylphosphinobiphenyl
Packaging: 100mg
Price: $75
Updated: 2021/12/16

Chem-Impex

Product number: 40764
Product name: 2-(Diphenylphosphino)biphenyl,98%(GC)
Purity: 98%(GC)
Packaging: 1G
Price: $32.48
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD140367
Product name: 2-(Diphenylphosphino)-biphenyl
Packaging: 2g
Price: $70
Updated: 2021/12/16

ChemScene

Product number: CS-W003792
Product name: 2-(Diphenylphosphino)biphenyl
Packaging: 25g
Price: $99
Updated: 2021/12/16

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2-(Diphenylphosphino)-biphenyl Chemical Properties,Usage,Production

Uses

2-(Diphenylphosphino)biphenyl is used as an organic chemical synthesis intermediate.

Uses

2-(Diphenylphosphino)biphenyl as ligand for suzuki reaction.

Synthesis

2113-51-1

829-85-6

13885-09-1

General procedure for the synthesis of 2-(diphenylphosphino)-biphenyl from 2-iodobiphenyl and diphenylphosphine: MCM-41-3N-Pd(0) catalyst (21 mg, 0.01 mmol), KOAc (1.5 mmol), and 2-iodobiphenyl (1.0 mmol if solid) were placed in a 20 mL Schlenk tube that had been pre oven-dried. The reaction vessel was evacuated and displaced three times with argon. Subsequently, 2-iodobiphenyl (1.0 mmol, if liquid), diphenylphosphine (1.2 mmol) and DMAc (1 mL) were added via syringe under argon protection. The reaction mixture was stirred at 130°C for 3 hours. After the reaction was completed, the mixture was cooled to room temperature, diluted with CH2Cl2 (20 mL) and filtered.The MCM-41-3N-Pd(0) catalyst was washed with distilled water (2 × 5 mL) and ethanol (2 × 5 mL) for next use. The filtrate was concentrated under vacuum and the residue was purified by fast column chromatography on silica gel to afford the target product 2-(diphenylphosphino)-biphenyl.

References

[1] Organic Letters, 2003, vol. 5, # 13, p. 2315 - 2318
[2] Applied Organometallic Chemistry, 2018, vol. 32, # 8,
[3] Journal of Organometallic Chemistry, 2018, vol. 866, p. 50 - 58

2-(Diphenylphosphino)-biphenyl Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(Diphenylphosphino)-biphenyl Suppliers

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View Lastest Price from 2-(Diphenylphosphino)-biphenyl manufacturers

Hebei Fengjia New Material Co., Ltd

Product: 2-(Diphenylphosphino)-biphenyl 13885-09-1
Price: US $3.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10000
Release date: 2024-08-16

Hebei Chuanghai Biotechnology Co., Ltd

Product: 2-(Diphenylphosphino)-biphenyl 13885-09-1
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-25

XINXIANG RUNYU MATERIAL CO., LTD.

Product: 2-(Diphenylphosphino)-biphenyl 13885-09-1
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 0.98
Supply Ability: 500KG
Release date: 2021-11-29

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