5-Fluoro-2-methoxyphenylboronic acid

Product Name: 5-Fluoro-2-methoxyphenylboronic acid
CAS No.: 179897-94-0
Chemical Name: 5-Fluoro-2-methoxyphenylboronic acid
Synonyms: AKOS BRN-0214;CHEMBRDG-BB 4202998;RARECHEM AH PB 0134;5-Fluoro-2-methoxyph;uoro-2-methoxyphenyL;2-Borono-4-fluoroanisole;2-Methoxy-5-Fluoro-Boronicacid;4-Fluoroanisole-2-boronic acid;5-Fluoro-2-methoxylboronic acid;5-FLUORO-2-METHOXYPHENYLBORONIC ACID
CBNumber: CB0228181
Molecular Formula: C7H8BFO3
Formula Weight: 169.95
MOL File: 179897-94-0.mol

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5-Fluoro-2-methoxyphenylboronic acid Property

Melting point:: 144-153 °C (lit.)
Boiling point:: 337.1±52.0 °C(Predicted)
Density: 1.26±0.1 g/cm3(Predicted)
storage temp.: Storage temp. 2-8°C
solubility: soluble in Methanol
pka: 7.52±0.58(Predicted)
form: Crystalline Powder
color: White
InChI: 1S/C7H8BFO3/c1-12-7-3-2-5(9)4-6(7)8(10)11/h2-4,10-11H,1H3
InChIKey: CCQKIRUMTHHPSX-UHFFFAOYSA-N
SMILES: COc1ccc(F)cc1B(O)O
CAS DataBase Reference: 179897-94-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-20/21/22
Safety Statements: 26-36/37/39-36-24/25
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29163990
Storage Class: 13 - Non Combustible Solids

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 483540
Product name: 5-Fluoro-2-methoxyphenylboronic acid
Purity: ≥95%
Packaging: 5g
Price: $66.5
Updated: 2023/06/20

Sigma-Aldrich

Product number: 483540
Product name: 5-Fluoro-2-methoxyphenylboronic acid
Purity: ≥95%
Packaging: 25g
Price: $240
Updated: 2023/06/20

TCI Chemical

Product number: F0775
Product name: 5-Fluoro-2-methoxyphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $69
Updated: 2025/07/31

TCI Chemical

Product number: F0775
Product name: 5-Fluoro-2-methoxyphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 25g
Price: $275
Updated: 2025/07/31

TRC

Product number: F595683
Product name: 5-Fluoro-2-methoxyphenylboronic acid
Packaging: 500mg
Price: $65
Updated: 2021/12/16

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5-Fluoro-2-methoxyphenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

White to off-white powder

Uses

5-Fluoro-2-methoxyphenylboronic Acid is an important building blocks in organic syntheses. A reagent for Suzuki coupling reactions and copper catalyzed arylation reactions. A bacterial mutagen.

Uses

Reactant for:• ;Suzuki couplings1,2• ;Copper catalyzed arylation3

Uses

suzuki reaction

Synthesis

There are two main methods to synthesize 5-fluoro-2-methoxyphenylboronic acid: 1) Reacting with p-fluoroanisole and n-butyllithium solution dissolved in THF at -60 . ??, then react with triisopropyl borate at -70 ?? and then acidify with hydrochloric acid to obtain; 2) Use 2-bromo-4-fluoroanisole and n-butyllithium solution dissolved in THF first. 2) obtained by reacting 2-bromo-4-fluoroanisole with n-butyllithium solution dissolved in THF at -78 ??, then reacting with trimethyl borate at room temperature, then acidified with hydrochloric acid and washed with ammonium chloride solution.

5-Fluoro-2-methoxyphenylboronic acid Preparation Products And Raw materials

Raw materials

4-Fluoroanisole Tetrahydrofuran Triisopropyl borate n-Butyllithium

Preparation Products

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5-Fluoro-2-methoxyphenylboronic acid Suppliers

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View Lastest Price from 5-Fluoro-2-methoxyphenylboronic acid manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: 5-Fluoro-2-methoxyphenylboronic acid 179897-94-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: 5-Fluoro-2-methoxyphenylboronic acid 179897-94-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

Zhuozhou Wenxi import and Export Co., Ltd

Product: 5-Fluoro-2-methoxyphenylboronic acid 179897-94-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-09

179897-94-0, 5-Fluoro-2-methoxyphenylboronic acidRelated Search:

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uoro-2-methoxyphenyL

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179897-94-0

179879-94-0

BORONIC ACID

Boronic Acids

Organometallic Reagents

Aryl

Boronic Acids and Derivatives

Furans

Aryl Boronic Acids

Boronic Acids

Boronic Acids and Derivatives

Chemical Synthesis

Disubstituted Aryl Boronic Acids

Organometallic Reagents

Alkoxy

Aryl

Organoborons

Boronic Acids

Boronic Acids and Derivatives

Substituted Boronic Acids

Boronic Acid

blocks

BoronicAcids

FluoroCompounds