ChemicalBook > CAS DataBase List > (Pentamethylcyclopentadienyl)iridium(III) chloride dimer
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer
Reaction- Product Name
- (Pentamethylcyclopentadienyl)iridium(III) chloride dimer
- CAS No.
- 12354-84-6
- Chemical Name
- (Pentamethylcyclopentadienyl)iridium(III) chloride dimer
- Synonyms
- iridium(III);[(η5-C5Me5)IrCl2]2;Dichloropentamethylcyclopentadienyliridiumdimer;Dichloro(pentamethylcyclopentadienyl)iridium(III);94.0%(T);[Cp*IrCl2]2;Ir(Cp-)Cl2]2;PentaMethylcyclopen;pentamethylcyclopentadienyliridium(iii) chloride;Pentamethylcyclopentadienyliridium( chloride dimer
- CBNumber
- CB0241678
- Molecular Formula
- C20H30Cl4Ir210*
- Formula Weight
- 796.7
- MOL File
- 12354-84-6.mol
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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Property
- Melting point:
- 245 °C (decomp)(Solv: chloroform (67-66-3); hexane (110-54-3))
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Chloroform (Sparingly), Methanol (Slightly)
- form
- crystal
- color
- orange
- Stability:
- Moisture Sensitive
- InChI
- InChI=1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
- InChIKey
- JDOHSXHCQARCAW-UHFFFAOYSA-J
- SMILES
- [C]1(C)[C](C)[C](C)[C](C)[C]1C.[C]1(C)[C](C)[C](C)[C](C)[C]1C.[Ir](Cl)Cl.[Ir](Cl)Cl |^1:0,2,4,6,8,10,12,14,16,18|
- CAS DataBase Reference
- 12354-84-6
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38-R36/37/38
- Safety Statements
- 37/39-26-S37/39-S26-24/25
- WGK Germany
- 3
- TSCA
- No
- HS Code
- 28439000
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 357537
- Product name
- Pentamethylcyclopentadienyliridium(III) chloride,dimer
- Purity
- 96%
- Packaging
- 100mg
- Price
- $80.87
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 357537
- Product name
- Pentamethylcyclopentadienyliridium(III) chloride,dimer
- Purity
- 96%
- Packaging
- 500mg
- Price
- $236
- Updated
- 2025/07/31
TCI Chemical
- Product number
- P1763
- Product name
- (Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer
- Purity
- >95.0%(T)
- Packaging
- 1g
- Price
- $400
- Updated
- 2025/07/31
Strem Chemicals
- Product number
- 77-1060
- Product name
- Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer, 98%
- Packaging
- 100mg
- Price
- $71
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 77-1060
- Product name
- Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer, 98%
- Packaging
- 500mg
- Price
- $279
- Updated
- 2024/03/01
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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Chemical Properties,Usage,Production
Reaction
- Iridium-catalyzed C-3 alkylation of oxindole with alcohols.
- Precursor to N-heterocyclic carbene catalyst effective for hydrogenation and alkylation of amines and alcohols.
- Precursor to efficient phosphine free catalyst for enantioselective hydrogenation of quinoline derivatives.
- Catalyst for oxidative C–H activation.
- Precursor to an effective water oxidation catalyst.
Chemical Properties
orange fine crystalline powder
Uses
Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is used as a precursor to catalysts for the asymmetric transfer hydrogenation of ketones. It is a catalyst for greener amine synthesis.
General Description
This product has been enhanced for catalytic efficiency.
reaction suitability
core: iridium
reagent type: catalyst
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (Pentamethylcyclopentadienyl)iridium(III) chloride dimer manufacturers
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
- Product
- (Pentamethylcyclopentadienyl)iridium(III) chloride dimer 12354-84-6
- Price
- US $2.00-5.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-06-17
Henan Aochuang Chemical Co.,Ltd.
- Product
- (Pentamethylcyclopentadienyl)iridium(III) chloride dimer 12354-84-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-30
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- (Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer 12354-84-6
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
12354-84-6, (Pentamethylcyclopentadienyl)iridium(III) chloride dimerRelated Search:
METHYLCYCLOPENTADIENE DIMER
Sodium chloride
alpha,alpha'-Dichloro-p-xylene
Tetraphenylcyclopentadienone
Dichloromethylphenylsilane
1,2,3,4,5-Pentamethylcyclopentadiene
Dichloroacetic acid
DILINOLEIC ACID
SODIUM CYCLOPENTADIENIDE
1,3-Cyclopentadiene
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Iridium
2-Chloro-5-chloromethylpyridine
Dichlorodimethylsilane
BENZAL CHLORIDE
Iridium(III) chloride hydrate
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer
ALKYLKETENE DIMER