Reaction
ChemicalBook > CAS DataBase List > (Pentamethylcyclopentadienyl)iridium(III) chloride dimer

(Pentamethylcyclopentadienyl)iridium(III) chloride dimer

Reaction
Product Name
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer
CAS No.
12354-84-6
Chemical Name
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer
Synonyms
iridium(III);[(η5-C5Me5)IrCl2]2;Dichloropentamethylcyclopentadienyliridiumdimer;Dichloro(pentamethylcyclopentadienyl)iridium(III);94.0%(T);Ir(Cp-)Cl2]2;PentaMethylcyclopen;pentamethylcyclopentadienyliridium(iii) chloride;Pentamethylcyclopentadienyliridium( chloride dimer;Pentamethylcyclopentadienyliridium(Ⅲ) chloride dimer
CBNumber
CB0241678
Molecular Formula
C20H30Cl4Ir210*
Formula Weight
796.7
MOL File
12354-84-6.mol
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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Property

Melting point:
245 °C (decomp)(Solv: chloroform (67-66-3); hexane (110-54-3))
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Sparingly), Methanol (Slightly)
form 
crystal
color 
orange
Stability:
Moisture Sensitive
CAS DataBase Reference
12354-84-6
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-R36/37/38
Safety Statements 
37/39-26-S37/39-S26-24/25
WGK Germany 
3
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
357537
Product name
Pentamethylcyclopentadienyliridium(III) chloride,dimer
Purity
96%
Packaging
100mg
Price
$85.3
Updated
2024/03/01
Sigma-Aldrich
Product number
357537
Product name
Pentamethylcyclopentadienyliridium(III) chloride,dimer
Purity
96%
Packaging
500mg
Price
$229
Updated
2024/03/01
TCI Chemical
Product number
P1763
Product name
(Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer
Purity
>95.0%(T)
Packaging
1g
Price
$243
Updated
2024/03/01
Alfa Aesar
Product number
045565
Product name
Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
Packaging
500mg
Price
$178
Updated
2023/06/20
Alfa Aesar
Product number
045565
Product name
Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
Packaging
2g
Price
$710
Updated
2023/06/20
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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Chemical Properties,Usage,Production

Reaction

  1. Iridium-catalyzed C-3 alkylation of oxindole with alcohols.
  2. Precursor to N-heterocyclic carbene catalyst effective for hydrogenation and alkylation of amines and alcohols.
  3. Precursor to efficient phosphine free catalyst for enantioselective hydrogenation of quinoline derivatives.
  4. Catalyst for oxidative C–H activation.
  5. Precursor to an effective water oxidation catalyst. 

Chemical Properties

orange fine crystalline powder

Uses

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is used as a precursor to catalysts for the asymmetric transfer hydrogenation of ketones. It is a catalyst for greener amine synthesis.

General Description

This product has been enhanced for catalytic efficiency.

(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Preparation Products And Raw materials

Raw materials

Preparation Products

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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Suppliers

Shaanxi Rock New Materials Co., Ltd.
Tel
0917-8888777, 3380777,18691786767; 15619786767
Email
xuya@bjrock.com
Country
China
ProdList
310
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62
Sinocompound Catalysts Co., Ltd.
Tel
0512-67216630 67216634
Fax
0512-56316689
Email
sales@sinocompound.com
Country
China
ProdList
278
Advantage
64
Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Fax
0550-5610690
Email
cynthiachem@163.com
Country
China
ProdList
335
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62
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2409
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58
Yunnan Precious Metals Laboratory Co., Ltd
Tel
871-13529192135 13529192135
Fax
0871-68329797
Email
changqiaowen@126.com
Country
China
ProdList
165
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58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
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View Lastest Price from (Pentamethylcyclopentadienyl)iridium(III) chloride dimer manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer 12354-84-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-30
Zhuozhou Wenxi import and Export Co., Ltd
Product
(Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer 12354-84-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Longyan Tianhua Biological Technology Co., Ltd
Product
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer 12354-84-6
Price
US $35.00/KG
Min. Order
1KG
Purity
99
Supply Ability
1000KG
Release date
2020-11-11

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