Reaction
ChemicalBook > CAS DataBase List > (Pentamethylcyclopentadienyl)iridium(III) chloride dimer

(Pentamethylcyclopentadienyl)iridium(III) chloride dimer

Reaction
Product Name
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer
CAS No.
12354-84-6
Chemical Name
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer
Synonyms
iridium(III);[(η5-C5Me5)IrCl2]2;Dichloropentamethylcyclopentadienyliridiumdimer;Dichloro(pentamethylcyclopentadienyl)iridium(III);94.0%(T);Ir(Cp-)Cl2]2;PentaMethylcyclopen;pentamethylcyclopentadienyliridium(iii) chloride;Pentamethylcyclopentadienyliridium( chloride dimer;Pentamethylcyclopentadienyliridium(Ⅲ) chloride dimer
CBNumber
CB0241678
Molecular Formula
C20H30Cl4Ir210*
Formula Weight
796.7
MOL File
12354-84-6.mol
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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Property

Melting point:
245 °C (decomp)(Solv: chloroform (67-66-3); hexane (110-54-3))
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Sparingly), Methanol (Slightly)
form 
crystal
color 
orange
Stability:
Moisture Sensitive
CAS DataBase Reference
12354-84-6
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-R36/37/38
Safety Statements 
37/39-26-S37/39-S26-24/25
WGK Germany 
3
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
357537
Product name
Pentamethylcyclopentadienyliridium(III) chloride,dimer
Purity
96%
Packaging
100mg
Price
$85.3
Updated
2024/03/01
Sigma-Aldrich
Product number
357537
Product name
Pentamethylcyclopentadienyliridium(III) chloride,dimer
Purity
96%
Packaging
500mg
Price
$229
Updated
2024/03/01
TCI Chemical
Product number
P1763
Product name
(Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer
Purity
>95.0%(T)
Packaging
1g
Price
$243
Updated
2024/03/01
Alfa Aesar
Product number
045565
Product name
Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
Packaging
500mg
Price
$178
Updated
2023/06/20
Alfa Aesar
Product number
045565
Product name
Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
Packaging
2g
Price
$710
Updated
2023/06/20
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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Chemical Properties,Usage,Production

Reaction

  1. Iridium-catalyzed C-3 alkylation of oxindole with alcohols.
  2. Precursor to N-heterocyclic carbene catalyst effective for hydrogenation and alkylation of amines and alcohols.
  3. Precursor to efficient phosphine free catalyst for enantioselective hydrogenation of quinoline derivatives.
  4. Catalyst for oxidative C–H activation.
  5. Precursor to an effective water oxidation catalyst. 

Chemical Properties

orange fine crystalline powder

Uses

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is used as a precursor to catalysts for the asymmetric transfer hydrogenation of ketones. It is a catalyst for greener amine synthesis.

General Description

This product has been enhanced for catalytic efficiency.

(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Preparation Products And Raw materials

Raw materials

Preparation Products

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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Suppliers

SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from (Pentamethylcyclopentadienyl)iridium(III) chloride dimer manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer 12354-84-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-30
Zhuozhou Wenxi import and Export Co., Ltd
Product
(Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer 12354-84-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Longyan Tianhua Biological Technology Co., Ltd
Product
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer 12354-84-6
Price
US $35.00/KG
Min. Order
1KG
Purity
99
Supply Ability
1000KG
Release date
2020-11-11

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