ChemicalBook > CAS DataBase List > 4-Bromo-2,6-dimethylaniline

4-Bromo-2,6-dimethylaniline

Product Name: 4-Bromo-2,6-dimethylaniline
CAS No.: 24596-19-8
Chemical Name: 4-Bromo-2,6-dimethylaniline
Synonyms: 4-BROMO-2,6-XYLIDINE;2,6-Dimethyl-4-bromoaniline;6-diMethylaniline;TIMTEC-BB SBB002410;4-Bromo-2,6-dimethyl;2,6-Xylidine, 4-bromo-;LABOTEST-BB LT01143222;4-BROMO-2,6-DIMETHYLANILINE;4-broMo-2,6-deMethylaniline;6-dimethylaniline4-Bromo-2,
CBNumber: CB0250184
Molecular Formula: C8H10BrN
Formula Weight: 200.08
MOL File: 24596-19-8.mol

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4-Bromo-2,6-dimethylaniline Property

Melting point:: 48-51 °C (lit.)
Boiling point:: 120°C 0,2mm
Density: 1.4423 (rough estimate)
refractive index: 1.5748 (estimate)
Flash point:: >230 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Chloroform, Methanol
pka: 3.60±0.10(Predicted)
form: Liquid
color: Clear yellow to orange to amber
BRN: 1936300
InChI: InChI=1S/C8H10BrN/c1-5-3-7(9)4-6(2)8(5)10/h3-4H,10H2,1-2H3
InChIKey: QGLAYJCJLHNIGJ-UHFFFAOYSA-N
SMILES: C1(N)=C(C)C=C(Br)C=C1C
CAS DataBase Reference: 24596-19-8(CAS DataBase Reference)
NIST Chemistry Reference: Benzenamine, 4-bromo-2,6-dimethyl-(24596-19-8)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 38-43-36/37/38-20/21/22
Safety Statements: 36/37-36/37/39-26
RIDADR: UN2811/6.1/III
WGK Germany: 3
F: 8-10-23
Hazard Note: Harmful
HazardClass: 6.1
HS Code: 29214990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H335May cause respiratory irritation

H351Suspected of causing cancer

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 192376
Product name: 4-Bromo-2,6-dimethylaniline
Purity: 98%
Packaging: 25g
Price: $104
Updated: 2025/07/31

Sigma-Aldrich

Product number: 192376
Product name: 4-Bromo-2,6-dimethylaniline
Purity: 98%
Packaging: 100g
Price: $267
Updated: 2025/07/31

TCI Chemical

Product number: B1909
Product name: 4-Bromo-2,6-dimethylaniline
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $66
Updated: 2025/07/31

TCI Chemical

Product number: B1909
Product name: 4-Bromo-2,6-dimethylaniline
Purity: >98.0%(GC)(T)
Packaging: 100g
Price: $258
Updated: 2025/07/31

TRC

Product number: B689225
Product name: 4-Bromo-2,6-xylidine
Packaging: 25g
Price: $150
Updated: 2021/12/16

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4-Bromo-2,6-dimethylaniline Chemical Properties,Usage,Production

Chemical Properties

brown crystals

Uses

4-Bromo-2,6-dimethylaniline has been used in the preparation of:

4-bromo-N-(1-(6-(1-isopropyl-1H-benzo[d]imidazol-2-yl)pyridin-2-yl)ethylidene)-2,6-dimethylbenzenamine
N-(4-Bromo-2,6-dimethylphenyl)-5-trimethylammoniumsalicylaldimine chloride
ethynyl-functionalized persistent perylene diimide-multichromophore

Reactions

4-Bromo-2,6-dimethylaniline has been shown to react with acid solutions to form hydrogen bromide gas and ammonium chloride crystals.

Synthesis

87-62-7

24596-19-8

The general procedure for the synthesis of 4-bromo-2,6-dimethylaniline from 2,6-dimethylaniline was as follows: 1-methoxy-3,5-dimethylbenzene (100 mg, 0.73 mmol), N-bromosuccinimide (NBS, 260 mg, 1.46 mmol), and a stainless steel ball (5 mm in diameter) were placed in a 10 mL stainless steel grinding jar. The ball milling reaction was carried out and the reaction process was monitored by thin layer chromatography (TLC) and proton nuclear magnetic resonance (1H NMR). Upon completion of the reaction, the reaction mixture was transferred to 30 mL of ethyl acetate and cooled at 0°C. The filtrate (containing product) and precipitate (spent succinimide) were obtained by filtration through filter paper and separated. The filtrate was concentrated under vacuum to give 250 mg (85% yield) of 4-bromo-2,6-dimethylaniline (2b) as a colorless powder. To test the efficiency of the large-scale reaction, monobromination was carried out under the same conditions using 1.3 g of 1-methoxy-3,5-dimethylbenzene for 1 h. The product was isolated in 87% yield. During the reaction, the grinding equipment was suspended and a small amount of sample was removed from the reaction tank for TLC and 1H NMR analysis, after which the reaction was continued, and the time of this operation was not included in the total reaction time.

References

[1] Tetrahedron Letters, 2005, vol. 46, # 51, p. 8959 - 8963
[2] Tetrahedron Letters, 2009, vol. 50, # 9, p. 1007 - 1009
[3] Synthetic Communications, 2010, vol. 40, # 5, p. 647 - 653
[4] Synthetic Communications, 2009, vol. 39, # 23, p. 4212 - 4220
[5] Journal fuer Praktische Chemie (Leipzig), 1988, vol. 330, # 2, p. 161 - 174

4-Bromo-2,6-dimethylaniline Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-Bromo-2,6-dimethylaniline manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd

Product: 4-bromo-2,6-dimethylaniline 24596-19-8
Price: US $0.00-0.00/kg
Min. Order: 25kg
Purity: 98%
Supply Ability: Customise
Release date: 2025-09-04

Hebei Fengjia New Material Co., Ltd

Product: 4-Bromo-2,6-dimethylaniline 24596-19-8
Price: US $3.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10000
Release date: 2024-09-04

Hebei Chuanghai Biotechnology Co., Ltd

Product: 4-Bromo-2,6-dimethylaniline 24596-19-8
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-18

24596-19-8, 4-Bromo-2,6-dimethylanilineRelated Search:

3,4-Dimethylaniline 2,6-Lutidine 2,6-Dimethylphenol 2,4-Dimethyl aniline DIMETHYLANILINE 4-Bromo-3-methylaniline 5-Bromo-2-methylaniline N,N-Dimethyl-p-toluidine 2,6-Dimethylaniline 3-Bromoaniline 3-Bromo-2-methylaniline N,N-Dimethylaniline 4-Bromo-2,6-difluoroaniline 4-Bromoaniline 4-BROMO-2,6-DICHLOROBENZOIC ACID 4-BROMO-2,6-DIMETHYLANISOLE 4-Bromo-3-fluorobenzonitrile 4-Bromo-3-fluorobenzaldehyde

TIMTEC-BB SBB002410

2,6-Dimethyl-4-bromoaniline

2,6-Xylidine, 4-bromo-

2-Amino-5-bromo-m-xylene, 4-Bromo-2,6-xylidine

4-BroMo-2,6-diMethylaniline, 97+%

4 - broMine - 2, 6 - diMethylaniline

Benzenamine, 4-bromo-2,6-dimethyl-

4-bromo-2,6-dimethylaniline,98%

4-Bromo-2,6-dimethyl-phenylamine

LABOTEST-BB LT01143222

4-BROMO-2,6-XYLIDINE

4-BROMO-2,6-DIMETHYLANILINE

4-Bromo-2,6-dimethylaniline 98%

4-BROMO-2,6-DIMETHYLANILINE (4-BROMO-2,6-XYLIDINE)

4-BROMO-2,6-DIMETHYLANILINE 99+%

2-Methyl-6-Ethylbenzenamine(6-Ethyl-o-toluidine)

4-bromo-2,6-dimethyl-Benzenamine

4-BroMo-2,6-diMethylaniline, 98% 25GR

4-BroMo-2,6-diMethylaniline, 98% 5GR

4-Bromo-2,6-dimethyl

6-diMethylaniline

4-Bromo-2,6-Dimethylaniline, 98% PS

4-broMo-2,6-deMethylaniline

4-Bromo-2,6-dimethylaniline &gt

4-Bromo-2,6-dimethylphenylamine (4-Bromo-2,6-dimethylaniline

6-dimethylaniline4-Bromo-2,

24596-19-8

BrC6H2CH32NH2

C8H10BrN

Amines

Building Blocks

Nitrogen Compounds

Organic Building Blocks

Anilines, Amides & Amines

Bromine Compounds

Benzenes

Aniline

Aromatic Halides (substituted)

bc0001