Aroma Uses in Perfume
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Piperonyl acetone

Aroma Uses in Perfume
Product Name
Piperonyl acetone
CAS No.
55418-52-5
Chemical Name
Piperonyl acetone
Synonyms
DULCINYL;4-(benzo[d][1,3]dioxol-5-yl)butan-2-one;PIPERONYLACETONE;FEMA 2701;HELIOTROPYL ACETONE;Piperonylacetone>Piperonyl acetone USP/EP/BP;4-(3,4-methylenedioxyphenyl)-2;3,4-METHYLENEDIOXYBENZYL ACETONE;Piperonyl acetone, 10 mM in DMSO
CBNumber
CB0328014
Molecular Formula
C11H12O3
Formula Weight
192.21
MOL File
55418-52-5.mol
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Piperonyl acetone Property

Melting point:
49-54 °C(lit.)
Boiling point:
176 °C17 mm Hg(lit.)
Density 
1.175±0.06 g/cm3(Predicted)
FEMA 
2701 | 4-(3,4-METHYLENEDIOXYPHENYL)-2-BUTANONE
refractive index 
1.52-1.522
Flash point:
>230 °F
storage temp. 
4°C
solubility 
Chloroform (Slightly), DMSO (Slightly)
form 
Solid
color 
Colourless crystals.
Odor
at 10.00 % in dipropylene glycol. sweet raspberry heliotrope powdery cotton candy
Odor Type
floral
JECFA Number
2048
BRN 
169843
InChIKey
TZJLGGWGVLADDN-UHFFFAOYSA-N
LogP
1.53
CAS DataBase Reference
55418-52-5(CAS DataBase Reference)
NIST Chemistry Reference
4-(3,4-Methylenedioxyphenyl)-2-butanone(55418-52-5)
EPA Substance Registry System
2-Butanone, 4-(1,3-benzodioxol-5-yl)- (55418-52-5)
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Safety

Safety Statements 
22-24/25
WGK Germany 
2
TSCA 
Yes
HS Code 
2914.19.0000
Toxicity
The acute oral LD50 value in rats was reported as 4Og/kg and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Wohl, 1974).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S114162
Product name
4-BENZO(1,3)DIOXOL-5-YL-BUTAN-2-ONE
Purity
Aldrich
Packaging
100mg
Price
$179
Updated
2024/03/01
TCI Chemical
Product number
P1089
Product name
Piperonylacetone
Purity
>98.0%(GC)
Packaging
25g
Price
$123
Updated
2024/03/01
Alfa Aesar
Product number
L06258
Product name
4-(3,4-Methylenedioxy)phenyl-2-butanone, 98%
Packaging
5g
Price
$42.65
Updated
2024/03/01
Alfa Aesar
Product number
L06258
Product name
4-(3,4-Methylenedioxy)phenyl-2-butanone, 98%
Packaging
25g
Price
$153.65
Updated
2024/03/01
TRC
Product number
P475345
Product name
PiperonylAcetone
Packaging
2.5g
Price
$75
Updated
2021/12/16
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Piperonyl acetone Chemical Properties,Usage,Production

Aroma

Intensely sweet, floral and very slightly woody-powdery odor reminiscent of the sweetfloral notes in Mimosa and Cassie. Also remotely reminiscent of Heliotrope.
The taste in dilutions below 50 ppm is sweet, somewhat fruity and "Cherry-pit"-like. Higher concentrations tend to show a somewhat bitter taste.

Uses in Perfume

For several decades well kept as a "secret" chemical this ketone is one of the most interest ing and successful condensation products from a perfumery point of view. Piperonyl acetone finds application in Lilac, Lily, Sweet Pea, Appleblossom, Mimosa, Cassie, Ylang-Ylang, Heliotrope, Carnation, etc. and is particularly interesting in lipstick perfumes, also because it blends well with lonones.
Piperonyl acetone finds use in flavor compositions for imitation Cherry ("pit flavor") in various fruit complexes. Occasionally as a modifier in Vanilla imitation. The concentration is about 8 to 45 ppm in finished products. The highest figures are usually in icecream, about 50 ppm.

Description

4-(3,4-Methylenedioxyphenyl)-2-butanone has an intensely sweet, floral, slightly woody odor. May be prepared by condensation of heliotropin with acetone, followed by hydrogenation in the presence of a palladium catalyst.

Chemical Properties

4-(3,4-Methylenedioxyphenyl)-2-butanone has an intensely sweet, floral, slightly woody odor reminiscent of raspberry, cotton candy (i.e., candy floss) with a cassie, heliotrope association.

Occurrence

Has apparently not been reported to occur in nature.

Definition

ChEBI: 4-(3,4-Methylenedioxyphenyl)-2-butanone is a member of benzodioxoles.

Preparation

By condensation of heliotropin with acetone, followed by hydrogenation in the presence of a palladium catalyst

Taste threshold values

Taste characteristics at 40 ppm: sweet, berry-like with spicy, jamy nuances

Metabolism

The oxygen-aromatic carbon link of aromatic ethers is generally biologically stable, and possible metabolites include the p-hydroxy derivative of the ether, the phenol or the p-hydroxyphenol (Williams, 1959). Ketones are not readily metabolized in the body. As a derivative of 2-butanone, piperonyl acetone might be expected to be partially reduced to the secondary alcohol and excreted as the glucuronide (Williams, 1959), since Saneyoshi (1911) isolated the glucuronide of 2-butanol from the urine of rabbits receiving methyl ethyl ketone.

Piperonyl acetone Preparation Products And Raw materials

Raw materials

Preparation Products

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Piperonyl acetone Suppliers

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View Lastest Price from Piperonyl acetone manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Piperonyl acetone 55418-52-5
Price
US $60.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2024-11-20
Hebei Weibang Biotechnology Co., Ltd
Product
Piperonyl acetone 55418-52-5
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100 mt
Release date
2024-11-12
Shandong Deshang Chemical Co., Ltd.
Product
Piperonyl acetone 55418-52-5
Price
US $8.00-5.30/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
10 tons
Release date
2024-06-21

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