ChemicalBook > CAS DataBase List > 7-(TRIFLUOROMETHYL)QUINOLINE

7-(TRIFLUOROMETHYL)QUINOLINE

Product Name
7-(TRIFLUOROMETHYL)QUINOLINE
CAS No.
325-14-4
Chemical Name
7-(TRIFLUOROMETHYL)QUINOLINE
Synonyms
7-Trrfluoromethylquinoline;7-(TRIFLUOROMETHYL)QUINOLINE;Quinoline, 7-(trifluoromethyl)-;7-(Trifluoromethyl)quinoline,97%
CBNumber
CB0347770
Molecular Formula
C10H6F3N
Formula Weight
197.16
MOL File
325-14-4.mol
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7-(TRIFLUOROMETHYL)QUINOLINE Property

Melting point:
65-67°C
Boiling point:
236.6℃ (762 Torr)
Density 
1.311±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
2.55±0.14(Predicted)
Appearance
White to off-white Solid
CAS DataBase Reference
325-14-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
HazardClass 
IRRITANT
HS Code 
2933499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
T895680
Product name
7-(Trifluoromethyl)quinoline
Packaging
100mg
Price
$60
Updated
2021/12/16
SynQuest Laboratories
Product number
3H32-3-0W
Product name
7-(Trifluoromethyl)quinoline
Purity
97%
Packaging
10g
Price
$832
Updated
2021/12/16
AK Scientific
Product number
N530
Product name
7-(Trifluoromethyl)quinoline
Packaging
1g
Price
$215
Updated
2021/12/16
Apolloscientific
Product number
PC520509
Product name
7-(Trifluoromethyl)quinoline
Purity
97%
Packaging
1g
Price
$80
Updated
2021/12/16
Matrix Scientific
Product number
023763
Product name
7-(Trifluoromethyl)quinoline
Purity
97%
Packaging
1g
Price
$123
Updated
2021/12/16
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7-(TRIFLUOROMETHYL)QUINOLINE Chemical Properties,Usage,Production

Chemical Properties

yellow powder

Synthesis

98-16-8

56-81-5

325-14-4

1. Concentrated sulfuric acid (13.7 g, 0.14 mol) was slowly added dropwise to glycerol (8.63 g, 0.094 mol) at a controlled temperature not exceeding 70 °C. 2. m-Trifluoromethylaniline (5.00 g, 0.031 mol) was added to the above mixture, and the reaction was heated up to 85 °C, and kept at 85 °C for 40 min. 3. Potassium iodide (0.30 g, 1.80 mmol), iodine (0.34 g, 1.34 mmol), and water (1.50 mL) were added in sequence, and the reaction system was heated up to 135 °C for 4 hours. 4. 1.80 mmol), iodine (0.34 g, 1.34 mmol) and water (1.50 mL) were added sequentially, and the reaction system was heated to 135 °C and the reaction was sustained for 4 h. 4. Upon completion of the reaction, it was cooled to room temperature, and the reaction mixture was quenched by pouring it into iced water and filtered through diatomaceous earth. 5. The filtrate was adjusted to a pH of 7 with ammonia, pumped, and the filtrate was extracted with ethyl acetate. 6. The organic phases were combined, dried over anhydrous sodium sulfate and concentrated under reduced pressure.7. The residue was purified by column chromatography to afford 7-trifluoromethylquinoline (3.50 g, 69% yield).

References

[1] Patent: CN108409649, 2018, A. Location in patent: Paragraph 0042; 0043; 0044
[2] Patent: US2010/234340, 2010, A1. Location in patent: Page/Page column 21

7-(TRIFLUOROMETHYL)QUINOLINE Preparation Products And Raw materials

Raw materials

Preparation Products

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7-(TRIFLUOROMETHYL)QUINOLINE Suppliers

J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Alfa Aesar
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400-6106006
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021-67582001/03/05
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saleschina@alfa-asia.com
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China
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Energy Chemical
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021-021-58432009 400-005-6266
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Capot Chemical Co., Ltd
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+86 (0) 571 85 58 67 18
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0086-571-85864795
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Shanghai Hanhong Scientific Co.,Ltd.
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021-54306202 13764082696
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info@hanhongsci.com
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Hangzhou Yuhao Chemical Technology Co., Ltd
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China
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Shanghai Run-Biotech Co., Ltd.
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Wuxi Zhangkun Biochemical Technology Co., Ltd.
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+86 0510-85629785
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+86 0510-85625359
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China
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Shanghai Meishui Chemical Technology Co., Ltd
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021-60549325 18616193163
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021-33250306
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China
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4526
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View Lastest Price from 7-(TRIFLUOROMETHYL)QUINOLINE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
7-(TRIFLUOROMETHYL)QUINOLINE 325-14-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Career Henan Chemical Co
Product
7-(TRIFLUOROMETHYL)QUINOLINE 325-14-4
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2020-02-04